1-(3,5-Di­nitro­benzo­yl)-4-(2-meth­oxy­phen­yl)piper­azine

In the title compound, C(18)H(18)N(4)O(6), the piperazine ring adopts a chair conformation, the amidic N atom is planar (sum of angles = 360°) and the non-amidic N atom is pyramidal (343°). There are no hydrogen bonds of any kind in the crystal, but the mol­ecules are linked by two independent π(nit...

Descripción completa

Detalles Bibliográficos
Autores principales: Harish Chinthal, Chayanna, Kavitha, Channappa N., Yathirajan, Hemmige S., Foro, Sabine, Glidewell, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462154/
https://www.ncbi.nlm.nih.gov/pubmed/36340013
http://dx.doi.org/10.1107/S2414314620015230
Descripción
Sumario:In the title compound, C(18)H(18)N(4)O(6), the piperazine ring adopts a chair conformation, the amidic N atom is planar (sum of angles = 360°) and the non-amidic N atom is pyramidal (343°). There are no hydrogen bonds of any kind in the crystal, but the mol­ecules are linked by two independent π(nitro­benzene)⋯π(meth­oxy­benzene) stacking inter­actions to form π-stacked sheets with inter-centroid separations of 3.8444 (12) and 3.9197 (12) Å. [Image: see text]

Ejemplares similares