1-(3,5-Di­nitro­benzo­yl)-4-(2-meth­oxy­phen­yl)piper­azine

In the title compound, C(18)H(18)N(4)O(6), the piperazine ring adopts a chair conformation, the amidic N atom is planar (sum of angles = 360°) and the non-amidic N atom is pyramidal (343°). There are no hydrogen bonds of any kind in the crystal, but the mol­ecules are linked by two independent π(nit...

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Autores principales: Harish Chinthal, Chayanna, Kavitha, Channappa N., Yathirajan, Hemmige S., Foro, Sabine, Glidewell, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462154/
https://www.ncbi.nlm.nih.gov/pubmed/36340013
http://dx.doi.org/10.1107/S2414314620015230
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author Harish Chinthal, Chayanna
Kavitha, Channappa N.
Yathirajan, Hemmige S.
Foro, Sabine
Glidewell, Christopher
author_facet Harish Chinthal, Chayanna
Kavitha, Channappa N.
Yathirajan, Hemmige S.
Foro, Sabine
Glidewell, Christopher
author_sort Harish Chinthal, Chayanna
collection PubMed
description In the title compound, C(18)H(18)N(4)O(6), the piperazine ring adopts a chair conformation, the amidic N atom is planar (sum of angles = 360°) and the non-amidic N atom is pyramidal (343°). There are no hydrogen bonds of any kind in the crystal, but the mol­ecules are linked by two independent π(nitro­benzene)⋯π(meth­oxy­benzene) stacking inter­actions to form π-stacked sheets with inter-centroid separations of 3.8444 (12) and 3.9197 (12) Å. [Image: see text]
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spelling pubmed-94621542022-11-04 1-(3,5-Di­nitro­benzo­yl)-4-(2-meth­oxy­phen­yl)piper­azine Harish Chinthal, Chayanna Kavitha, Channappa N. Yathirajan, Hemmige S. Foro, Sabine Glidewell, Christopher IUCrdata Data Reports In the title compound, C(18)H(18)N(4)O(6), the piperazine ring adopts a chair conformation, the amidic N atom is planar (sum of angles = 360°) and the non-amidic N atom is pyramidal (343°). There are no hydrogen bonds of any kind in the crystal, but the mol­ecules are linked by two independent π(nitro­benzene)⋯π(meth­oxy­benzene) stacking inter­actions to form π-stacked sheets with inter-centroid separations of 3.8444 (12) and 3.9197 (12) Å. [Image: see text] International Union of Crystallography 2020-11-20 /pmc/articles/PMC9462154/ /pubmed/36340013 http://dx.doi.org/10.1107/S2414314620015230 Text en © Harish Chinthal et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Harish Chinthal, Chayanna
Kavitha, Channappa N.
Yathirajan, Hemmige S.
Foro, Sabine
Glidewell, Christopher
1-(3,5-Di­nitro­benzo­yl)-4-(2-meth­oxy­phen­yl)piper­azine
title 1-(3,5-Di­nitro­benzo­yl)-4-(2-meth­oxy­phen­yl)piper­azine
title_full 1-(3,5-Di­nitro­benzo­yl)-4-(2-meth­oxy­phen­yl)piper­azine
title_fullStr 1-(3,5-Di­nitro­benzo­yl)-4-(2-meth­oxy­phen­yl)piper­azine
title_full_unstemmed 1-(3,5-Di­nitro­benzo­yl)-4-(2-meth­oxy­phen­yl)piper­azine
title_short 1-(3,5-Di­nitro­benzo­yl)-4-(2-meth­oxy­phen­yl)piper­azine
title_sort 1-(3,5-di­nitro­benzo­yl)-4-(2-meth­oxy­phen­yl)piper­azine
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462154/
https://www.ncbi.nlm.nih.gov/pubmed/36340013
http://dx.doi.org/10.1107/S2414314620015230
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