cis-{1-Butyl-3-[2-(phenyl­sulfan­yl)eth­yl]-4-imidazolin-2-yl-κ(2) C (2),S′}di­chlorido­platinum(II)

The asymmetric unit of the title compound, [PtCl(2)(C(15)H(20)N(2)S)], comprises one Pt(II) ion, one N-heterocyclic carbene(NHC)-thio­ether ligand and two chloride ions. The Pt(II) ion is four-coordinated by one C atom and one S atom of the NHC-thio­ether ligand, and by two chloride ions, forming an...

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Detalles Bibliográficos
Autores principales: Liang, Bing-Bing, Xiong, Hong-Gang, Hong, Wan-Yu, Yao, Hua-Gang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462157/
https://www.ncbi.nlm.nih.gov/pubmed/36340012
http://dx.doi.org/10.1107/S2414314620014339
Descripción
Sumario:The asymmetric unit of the title compound, [PtCl(2)(C(15)H(20)N(2)S)], comprises one Pt(II) ion, one N-heterocyclic carbene(NHC)-thio­ether ligand and two chloride ions. The Pt(II) ion is four-coordinated by one C atom and one S atom of the NHC-thio­ether ligand, and by two chloride ions, forming an approximately square-planar geometry. In the crystal, the mol­ecules are linked via C—H⋯Cl and C—H⋯π inter­actions, forming a layer parallel to the ab plane. [Image: see text]

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