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cis-{1-Butyl-3-[2-(phenylsulfanyl)ethyl]-4-imidazolin-2-yl-κ(2) C (2),S′}dichloridoplatinum(II)
The asymmetric unit of the title compound, [PtCl(2)(C(15)H(20)N(2)S)], comprises one Pt(II) ion, one N-heterocyclic carbene(NHC)-thioether ligand and two chloride ions. The Pt(II) ion is four-coordinated by one C atom and one S atom of the NHC-thioether ligand, and by two chloride ions, forming an...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462157/ https://www.ncbi.nlm.nih.gov/pubmed/36340012 http://dx.doi.org/10.1107/S2414314620014339 |
| _version_ | 1784787117909475328 |
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| author | Liang, Bing-Bing Xiong, Hong-Gang Hong, Wan-Yu Yao, Hua-Gang |
| author_facet | Liang, Bing-Bing Xiong, Hong-Gang Hong, Wan-Yu Yao, Hua-Gang |
| author_sort | Liang, Bing-Bing |
| collection | PubMed |
| description | The asymmetric unit of the title compound, [PtCl(2)(C(15)H(20)N(2)S)], comprises one Pt(II) ion, one N-heterocyclic carbene(NHC)-thioether ligand and two chloride ions. The Pt(II) ion is four-coordinated by one C atom and one S atom of the NHC-thioether ligand, and by two chloride ions, forming an approximately square-planar geometry. In the crystal, the molecules are linked via C—H⋯Cl and C—H⋯π interactions, forming a layer parallel to the ab plane. [Image: see text] |
| format | Online Article Text |
| id | pubmed-9462157 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2020 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-94621572022-11-04 cis-{1-Butyl-3-[2-(phenylsulfanyl)ethyl]-4-imidazolin-2-yl-κ(2) C (2),S′}dichloridoplatinum(II) Liang, Bing-Bing Xiong, Hong-Gang Hong, Wan-Yu Yao, Hua-Gang IUCrdata Data Reports The asymmetric unit of the title compound, [PtCl(2)(C(15)H(20)N(2)S)], comprises one Pt(II) ion, one N-heterocyclic carbene(NHC)-thioether ligand and two chloride ions. The Pt(II) ion is four-coordinated by one C atom and one S atom of the NHC-thioether ligand, and by two chloride ions, forming an approximately square-planar geometry. In the crystal, the molecules are linked via C—H⋯Cl and C—H⋯π interactions, forming a layer parallel to the ab plane. [Image: see text] International Union of Crystallography 2020-11-03 /pmc/articles/PMC9462157/ /pubmed/36340012 http://dx.doi.org/10.1107/S2414314620014339 Text en © Liang et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Liang, Bing-Bing Xiong, Hong-Gang Hong, Wan-Yu Yao, Hua-Gang cis-{1-Butyl-3-[2-(phenylsulfanyl)ethyl]-4-imidazolin-2-yl-κ(2) C (2),S′}dichloridoplatinum(II) |
| title |
cis-{1-Butyl-3-[2-(phenylsulfanyl)ethyl]-4-imidazolin-2-yl-κ(2)
C
(2),S′}dichloridoplatinum(II) |
| title_full |
cis-{1-Butyl-3-[2-(phenylsulfanyl)ethyl]-4-imidazolin-2-yl-κ(2)
C
(2),S′}dichloridoplatinum(II) |
| title_fullStr |
cis-{1-Butyl-3-[2-(phenylsulfanyl)ethyl]-4-imidazolin-2-yl-κ(2)
C
(2),S′}dichloridoplatinum(II) |
| title_full_unstemmed |
cis-{1-Butyl-3-[2-(phenylsulfanyl)ethyl]-4-imidazolin-2-yl-κ(2)
C
(2),S′}dichloridoplatinum(II) |
| title_short |
cis-{1-Butyl-3-[2-(phenylsulfanyl)ethyl]-4-imidazolin-2-yl-κ(2)
C
(2),S′}dichloridoplatinum(II) |
| title_sort | cis-{1-butyl-3-[2-(phenylsulfanyl)ethyl]-4-imidazolin-2-yl-κ(2)
c
(2),s′}dichloridoplatinum(ii) |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462157/ https://www.ncbi.nlm.nih.gov/pubmed/36340012 http://dx.doi.org/10.1107/S2414314620014339 |
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