(4′-Chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)bis(nitrato-κO)zinc(II)

In the title complex, [Zn(C(15)H(10)ClN(3))(NO(3))(2)], the central zinc(II) atom is penta­coordinated by two O-bonded nitrate ions and three N atoms of the 4′-chloro-2,2′:6′,2′′-terpyridine ligand in a slightly distorted trigonal–bipyramidal shape. The main feature of the title complex packing is t...

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Detalles Bibliográficos
Autores principales: Adrian, Rafael A., Canales, Daniela, Arman, Hadi D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462161/
https://www.ncbi.nlm.nih.gov/pubmed/36339026
http://dx.doi.org/10.1107/S2414314620013449
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author Adrian, Rafael A.
Canales, Daniela
Arman, Hadi D.
author_facet Adrian, Rafael A.
Canales, Daniela
Arman, Hadi D.
author_sort Adrian, Rafael A.
collection PubMed
description In the title complex, [Zn(C(15)H(10)ClN(3))(NO(3))(2)], the central zinc(II) atom is penta­coordinated by two O-bonded nitrate ions and three N atoms of the 4′-chloro-2,2′:6′,2′′-terpyridine ligand in a slightly distorted trigonal–bipyramidal shape. The main feature of the title complex packing is the presence of offset π–π inter­actions between the terpyridine rings in different layers. This structure constitutes the first known example of a zinc(II) 4-chloro­terpyridine complex with coordinating nitrate ions. [Image: see text]
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spelling pubmed-94621612022-11-04 (4′-Chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)bis(nitrato-κO)zinc(II) Adrian, Rafael A. Canales, Daniela Arman, Hadi D. IUCrdata Data Reports In the title complex, [Zn(C(15)H(10)ClN(3))(NO(3))(2)], the central zinc(II) atom is penta­coordinated by two O-bonded nitrate ions and three N atoms of the 4′-chloro-2,2′:6′,2′′-terpyridine ligand in a slightly distorted trigonal–bipyramidal shape. The main feature of the title complex packing is the presence of offset π–π inter­actions between the terpyridine rings in different layers. This structure constitutes the first known example of a zinc(II) 4-chloro­terpyridine complex with coordinating nitrate ions. [Image: see text] International Union of Crystallography 2020-10-13 /pmc/articles/PMC9462161/ /pubmed/36339026 http://dx.doi.org/10.1107/S2414314620013449 Text en © Adrian et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Adrian, Rafael A.
Canales, Daniela
Arman, Hadi D.
(4′-Chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)bis(nitrato-κO)zinc(II)
title (4′-Chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)bis(nitrato-κO)zinc(II)
title_full (4′-Chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)bis(nitrato-κO)zinc(II)
title_fullStr (4′-Chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)bis(nitrato-κO)zinc(II)
title_full_unstemmed (4′-Chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)bis(nitrato-κO)zinc(II)
title_short (4′-Chloro-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)bis(nitrato-κO)zinc(II)
title_sort (4′-chloro-2,2′:6′,2′′-terpyridine-κ(3) n,n′,n′′)bis(nitrato-κo)zinc(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462161/
https://www.ncbi.nlm.nih.gov/pubmed/36339026
http://dx.doi.org/10.1107/S2414314620013449
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AT armanhadid 4chloro2262terpyridinek3nnnbisnitratokozincii

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