catena-Poly[[chlorido­tris­(1,3-thia­zolidine-2-thione-κS)cadmium(II)]-μ-chlorido]

The synthesis and characterization of poly[di­chlorido­tri(1,3-thia­zolidine-2-thione)cadmium(II)], [CdCl(2)(C(3)H(5)NS(2))(3)]( n ), prepared from CdCl(2)·H(2)O and C(3)H(5)NS(2) (tzdSH) in a 1:3 ratio, are described. The Cd(II) cation is coordinated by three 1,3-thia­zolidine-2-thione mol­ecules a...

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Detalles Bibliográficos
Autores principales: Diop, Aboubacar, Diop, Tidiane, Kama, Antoine Blaise, Diop, Cheikh Abdou Khadre, Tumanov, Nikolay
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462165/
https://www.ncbi.nlm.nih.gov/pubmed/36339031
http://dx.doi.org/10.1107/S2414314620014236
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author Diop, Aboubacar
Diop, Tidiane
Kama, Antoine Blaise
Diop, Cheikh Abdou Khadre
Tumanov, Nikolay
author_facet Diop, Aboubacar
Diop, Tidiane
Kama, Antoine Blaise
Diop, Cheikh Abdou Khadre
Tumanov, Nikolay
author_sort Diop, Aboubacar
collection PubMed
description The synthesis and characterization of poly[di­chlorido­tri(1,3-thia­zolidine-2-thione)cadmium(II)], [CdCl(2)(C(3)H(5)NS(2))(3)]( n ), prepared from CdCl(2)·H(2)O and C(3)H(5)NS(2) (tzdSH) in a 1:3 ratio, are described. The Cd(II) cation is coordinated by three 1,3-thia­zolidine-2-thione mol­ecules and three Cl(−) anions in a distorted octa­hedral environment. The Cd metal centres are connected via Cl(−) ligands, creating polymeric chains running along the a-axis direction. The conformation of the chains is stabilized by N—H⋯Cl hydrogen bonds. [Image: see text]
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spelling pubmed-94621652022-11-04 catena-Poly[[chlorido­tris­(1,3-thia­zolidine-2-thione-κS)cadmium(II)]-μ-chlorido] Diop, Aboubacar Diop, Tidiane Kama, Antoine Blaise Diop, Cheikh Abdou Khadre Tumanov, Nikolay IUCrdata Data Reports The synthesis and characterization of poly[di­chlorido­tri(1,3-thia­zolidine-2-thione)cadmium(II)], [CdCl(2)(C(3)H(5)NS(2))(3)]( n ), prepared from CdCl(2)·H(2)O and C(3)H(5)NS(2) (tzdSH) in a 1:3 ratio, are described. The Cd(II) cation is coordinated by three 1,3-thia­zolidine-2-thione mol­ecules and three Cl(−) anions in a distorted octa­hedral environment. The Cd metal centres are connected via Cl(−) ligands, creating polymeric chains running along the a-axis direction. The conformation of the chains is stabilized by N—H⋯Cl hydrogen bonds. [Image: see text] International Union of Crystallography 2020-10-30 /pmc/articles/PMC9462165/ /pubmed/36339031 http://dx.doi.org/10.1107/S2414314620014236 Text en © Diop et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Diop, Aboubacar
Diop, Tidiane
Kama, Antoine Blaise
Diop, Cheikh Abdou Khadre
Tumanov, Nikolay
catena-Poly[[chlorido­tris­(1,3-thia­zolidine-2-thione-κS)cadmium(II)]-μ-chlorido]
title catena-Poly[[chlorido­tris­(1,3-thia­zolidine-2-thione-κS)cadmium(II)]-μ-chlorido]
title_full catena-Poly[[chlorido­tris­(1,3-thia­zolidine-2-thione-κS)cadmium(II)]-μ-chlorido]
title_fullStr catena-Poly[[chlorido­tris­(1,3-thia­zolidine-2-thione-κS)cadmium(II)]-μ-chlorido]
title_full_unstemmed catena-Poly[[chlorido­tris­(1,3-thia­zolidine-2-thione-κS)cadmium(II)]-μ-chlorido]
title_short catena-Poly[[chlorido­tris­(1,3-thia­zolidine-2-thione-κS)cadmium(II)]-μ-chlorido]
title_sort catena-poly[[chlorido­tris­(1,3-thia­zolidine-2-thione-κs)cadmium(ii)]-μ-chlorido]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462165/
https://www.ncbi.nlm.nih.gov/pubmed/36339031
http://dx.doi.org/10.1107/S2414314620014236
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