6-[(2-Hy­droxy-5-methyl­anilino)methyl­idene]-4-nitro­cyclo­hexa-2,4-dien-1-one

The title compound, C(14)H(12)N(2)O(4), is nearly planar with a dihedral angle between the aromatic rings of 1.41 (8)°. The phenolic O atom is deprotonated and the N atom of the azomethine unit carries the proton, thereby forming an intra­molecular N—H⋯O hydrogen bond. In the crystal, the mol­ecules...

Descripción completa

Detalles Bibliográficos
Autores principales: Böhme, Uwe, Fels, Sabine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462168/
https://www.ncbi.nlm.nih.gov/pubmed/36339025
http://dx.doi.org/10.1107/S241431462001384X
_version_ 1784787120596975616
author Böhme, Uwe
Fels, Sabine
author_facet Böhme, Uwe
Fels, Sabine
author_sort Böhme, Uwe
collection PubMed
description The title compound, C(14)H(12)N(2)O(4), is nearly planar with a dihedral angle between the aromatic rings of 1.41 (8)°. The phenolic O atom is deprotonated and the N atom of the azomethine unit carries the proton, thereby forming an intra­molecular N—H⋯O hydrogen bond. In the crystal, the mol­ecules form inversion dimers via pairwise O—H⋯O hydrogen bonds. [Image: see text]
format Online
Article
Text
id pubmed-9462168
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-94621682022-11-04 6-[(2-Hy­droxy-5-methyl­anilino)methyl­idene]-4-nitro­cyclo­hexa-2,4-dien-1-one Böhme, Uwe Fels, Sabine IUCrdata Data Reports The title compound, C(14)H(12)N(2)O(4), is nearly planar with a dihedral angle between the aromatic rings of 1.41 (8)°. The phenolic O atom is deprotonated and the N atom of the azomethine unit carries the proton, thereby forming an intra­molecular N—H⋯O hydrogen bond. In the crystal, the mol­ecules form inversion dimers via pairwise O—H⋯O hydrogen bonds. [Image: see text] International Union of Crystallography 2020-10-23 /pmc/articles/PMC9462168/ /pubmed/36339025 http://dx.doi.org/10.1107/S241431462001384X Text en © Böhme and Fels 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Böhme, Uwe
Fels, Sabine
6-[(2-Hy­droxy-5-methyl­anilino)methyl­idene]-4-nitro­cyclo­hexa-2,4-dien-1-one
title 6-[(2-Hy­droxy-5-methyl­anilino)methyl­idene]-4-nitro­cyclo­hexa-2,4-dien-1-one
title_full 6-[(2-Hy­droxy-5-methyl­anilino)methyl­idene]-4-nitro­cyclo­hexa-2,4-dien-1-one
title_fullStr 6-[(2-Hy­droxy-5-methyl­anilino)methyl­idene]-4-nitro­cyclo­hexa-2,4-dien-1-one
title_full_unstemmed 6-[(2-Hy­droxy-5-methyl­anilino)methyl­idene]-4-nitro­cyclo­hexa-2,4-dien-1-one
title_short 6-[(2-Hy­droxy-5-methyl­anilino)methyl­idene]-4-nitro­cyclo­hexa-2,4-dien-1-one
title_sort 6-[(2-hy­droxy-5-methyl­anilino)methyl­idene]-4-nitro­cyclo­hexa-2,4-dien-1-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462168/
https://www.ncbi.nlm.nih.gov/pubmed/36339025
http://dx.doi.org/10.1107/S241431462001384X
work_keys_str_mv AT bohmeuwe 62hydroxy5methylanilinomethylidene4nitrocyclohexa24dien1one
AT felssabine 62hydroxy5methylanilinomethylidene4nitrocyclohexa24dien1one

Ejemplares similares