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Bis(benzo[h]quinolin-10-olato-κ(2) N,O)bromidomanganese(III)

The title compound, [MnBr(C(13)H(8)NO)(2)], consists of a manganese(III) atom, which is coordinated by one bromido and two benzo[h]quinolin-10-olato ligands. The Mn(III) complex exhibits a distorted square-pyramidal coordination geometry with the Br ligand in the apical position. Neighbouring comple...

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Detalles Bibliográficos
Autores principales: Papa, Veronica, Spannenberg, Anke, Beller, Matthias, Junge, Kathrin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462173/
https://www.ncbi.nlm.nih.gov/pubmed/36337335
http://dx.doi.org/10.1107/S2414314620015709
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author Papa, Veronica
Spannenberg, Anke
Beller, Matthias
Junge, Kathrin
author_facet Papa, Veronica
Spannenberg, Anke
Beller, Matthias
Junge, Kathrin
author_sort Papa, Veronica
collection PubMed
description The title compound, [MnBr(C(13)H(8)NO)(2)], consists of a manganese(III) atom, which is coordinated by one bromido and two benzo[h]quinolin-10-olato ligands. The Mn(III) complex exhibits a distorted square-pyramidal coordination geometry with the Br ligand in the apical position. Neighbouring complexes are held together by π–π inter­actions and weak C—H⋯Br hydrogen bonds. [Image: see text]
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spelling pubmed-94621732022-11-04 Bis(benzo[h]quinolin-10-olato-κ(2) N,O)bromidomanganese(III) Papa, Veronica Spannenberg, Anke Beller, Matthias Junge, Kathrin IUCrdata Data Reports The title compound, [MnBr(C(13)H(8)NO)(2)], consists of a manganese(III) atom, which is coordinated by one bromido and two benzo[h]quinolin-10-olato ligands. The Mn(III) complex exhibits a distorted square-pyramidal coordination geometry with the Br ligand in the apical position. Neighbouring complexes are held together by π–π inter­actions and weak C—H⋯Br hydrogen bonds. [Image: see text] International Union of Crystallography 2020-12-04 /pmc/articles/PMC9462173/ /pubmed/36337335 http://dx.doi.org/10.1107/S2414314620015709 Text en © Papa et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Papa, Veronica
Spannenberg, Anke
Beller, Matthias
Junge, Kathrin
Bis(benzo[h]quinolin-10-olato-κ(2) N,O)bromidomanganese(III)
title Bis(benzo[h]quinolin-10-olato-κ(2) N,O)bromidomanganese(III)
title_full Bis(benzo[h]quinolin-10-olato-κ(2) N,O)bromidomanganese(III)
title_fullStr Bis(benzo[h]quinolin-10-olato-κ(2) N,O)bromidomanganese(III)
title_full_unstemmed Bis(benzo[h]quinolin-10-olato-κ(2) N,O)bromidomanganese(III)
title_short Bis(benzo[h]quinolin-10-olato-κ(2) N,O)bromidomanganese(III)
title_sort bis(benzo[h]quinolin-10-olato-κ(2) n,o)bromidomanganese(iii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462173/
https://www.ncbi.nlm.nih.gov/pubmed/36337335
http://dx.doi.org/10.1107/S2414314620015709
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