Ethyl α-l-sorboside

Ethyl l-sorboside, C(8)H(16)O(6), was prepared from the rare sugar l-sorbose, C(6)H(12)O(6), and crystallized. It was confirmed that ethyl l-sorboside formed α-pyran­ose with a (2) C (5) conformation. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, forming a three-dimensional network....

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Autores principales: Nagayama, Natsumi, Taniguchi, Norito, Matsumoto, Mao, Takeshita, Kei, Ishii, Tomohiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462176/
https://www.ncbi.nlm.nih.gov/pubmed/36337337
http://dx.doi.org/10.1107/S2414314620016259
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author Nagayama, Natsumi
Taniguchi, Norito
Matsumoto, Mao
Takeshita, Kei
Ishii, Tomohiko
author_facet Nagayama, Natsumi
Taniguchi, Norito
Matsumoto, Mao
Takeshita, Kei
Ishii, Tomohiko
author_sort Nagayama, Natsumi
collection PubMed
description Ethyl l-sorboside, C(8)H(16)O(6), was prepared from the rare sugar l-sorbose, C(6)H(12)O(6), and crystallized. It was confirmed that ethyl l-sorboside formed α-pyran­ose with a (2) C (5) conformation. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, forming a three-dimensional network. The unit-cell volume of the title ethyl α-l-sorboside is 940.63 Å(3) (Z = 4), which is about 194.69 Å(3) (26.1%) bigger than that of l-sorbose [745.94 Å(3) (Z = 4)]. [Image: see text]
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spelling pubmed-94621762022-11-04 Ethyl α-l-sorboside Nagayama, Natsumi Taniguchi, Norito Matsumoto, Mao Takeshita, Kei Ishii, Tomohiko IUCrdata Data Reports Ethyl l-sorboside, C(8)H(16)O(6), was prepared from the rare sugar l-sorbose, C(6)H(12)O(6), and crystallized. It was confirmed that ethyl l-sorboside formed α-pyran­ose with a (2) C (5) conformation. In the crystal, mol­ecules are linked by O—H⋯O hydrogen bonds, forming a three-dimensional network. The unit-cell volume of the title ethyl α-l-sorboside is 940.63 Å(3) (Z = 4), which is about 194.69 Å(3) (26.1%) bigger than that of l-sorbose [745.94 Å(3) (Z = 4)]. [Image: see text] International Union of Crystallography 2020-12-18 /pmc/articles/PMC9462176/ /pubmed/36337337 http://dx.doi.org/10.1107/S2414314620016259 Text en © Nagayama et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Nagayama, Natsumi
Taniguchi, Norito
Matsumoto, Mao
Takeshita, Kei
Ishii, Tomohiko
Ethyl α-l-sorboside
title Ethyl α-l-sorboside
title_full Ethyl α-l-sorboside
title_fullStr Ethyl α-l-sorboside
title_full_unstemmed Ethyl α-l-sorboside
title_short Ethyl α-l-sorboside
title_sort ethyl α-l-sorboside
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462176/
https://www.ncbi.nlm.nih.gov/pubmed/36337337
http://dx.doi.org/10.1107/S2414314620016259
work_keys_str_mv AT nagayamanatsumi ethylalsorboside
AT taniguchinorito ethylalsorboside
AT matsumotomao ethylalsorboside
AT takeshitakei ethylalsorboside
AT ishiitomohiko ethylalsorboside

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