2-(Octa­decyl­sulfan­yl)-1,3-thia­zole

The title compound, C(21)H(39)NS(2), crystallizes with two mol­ecules in the asymmetric unit, both having a linear 18-carbon alkyl chain bound through a thio­ether group. No π–π stacking or hydrogen bonding is observed. The orientation of the alkyl chains facilitates inter­molecular inter­actions be...

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Detalles Bibliográficos
Autores principales: Muller II, Joseph E., Osborn, Laura R., Traver, Joseph R., Hillesheim, Patrick C., Zeller, Matthias, Mirjafari, Arsalan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462184/
https://www.ncbi.nlm.nih.gov/pubmed/36340840
http://dx.doi.org/10.1107/S2414314620001704
Descripción
Sumario:The title compound, C(21)H(39)NS(2), crystallizes with two mol­ecules in the asymmetric unit, both having a linear 18-carbon alkyl chain bound through a thio­ether group. No π–π stacking or hydrogen bonding is observed. The orientation of the alkyl chains facilitates inter­molecular inter­actions between te chains. The structure is metrically ortho­rhom­bic but crystallizes in the monoclinic space group P2(1) and was found to be twinned by pseudomerohedry (emulating ortho­rhom­bic symmetry) and by inversion. The twin factions refined to 0.37 (4), 0.13 (4), 0.31 (5), and 0.19 (4). [Image: see text]

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