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1,4-Bis­(4-meth­oxy­phen­yl)naphthalene

The title naphthalene derivative, C(24)H(20)O(2), features 4-methy­oxy-substituted benzene rings in the 1 and 4 positions of the naphthalene ring system. There are two crystallographically independent mol­ecules (A and B) in asymmetric unit. The independent mol­ecules have very similar conformations...

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Detalles Bibliográficos
Autores principales: Manickam, R., Jagadeesan, G., Karunakaran, J., Srinivasan, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462186/
https://www.ncbi.nlm.nih.gov/pubmed/36340833
http://dx.doi.org/10.1107/S2414314620002126
Descripción
Sumario:The title naphthalene derivative, C(24)H(20)O(2), features 4-methy­oxy-substituted benzene rings in the 1 and 4 positions of the naphthalene ring system. There are two crystallographically independent mol­ecules (A and B) in asymmetric unit. The independent mol­ecules have very similar conformations in which the naphthalene ring systems are only slightly bent, exhibiting dihedral angles between the constituent benzene rings of 3.76 (15) and 3.39 (15)° for A and B, respectively. The pendent 4-methyoxybenzene rings are splayed out of the plane through the naphthalene ring system to which they are connected [range of dihedral angles = 59.63 (13) to 67.09 (13)°]. In the crystal, the mol­ecular packing is consolidated by inter­molecular C—H⋯π inter­actions, leading to supra­molecular chains along the b axis. The chains assemble without directional inter­actions between them. [Image: see text]