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1,4-Bis(4-methoxyphenyl)naphthalene
The title naphthalene derivative, C(24)H(20)O(2), features 4-methyoxy-substituted benzene rings in the 1 and 4 positions of the naphthalene ring system. There are two crystallographically independent molecules (A and B) in asymmetric unit. The independent molecules have very similar conformations...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462186/ https://www.ncbi.nlm.nih.gov/pubmed/36340833 http://dx.doi.org/10.1107/S2414314620002126 |
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author | Manickam, R. Jagadeesan, G. Karunakaran, J. Srinivasan, G. |
author_facet | Manickam, R. Jagadeesan, G. Karunakaran, J. Srinivasan, G. |
author_sort | Manickam, R. |
collection | PubMed |
description | The title naphthalene derivative, C(24)H(20)O(2), features 4-methyoxy-substituted benzene rings in the 1 and 4 positions of the naphthalene ring system. There are two crystallographically independent molecules (A and B) in asymmetric unit. The independent molecules have very similar conformations in which the naphthalene ring systems are only slightly bent, exhibiting dihedral angles between the constituent benzene rings of 3.76 (15) and 3.39 (15)° for A and B, respectively. The pendent 4-methyoxybenzene rings are splayed out of the plane through the naphthalene ring system to which they are connected [range of dihedral angles = 59.63 (13) to 67.09 (13)°]. In the crystal, the molecular packing is consolidated by intermolecular C—H⋯π interactions, leading to supramolecular chains along the b axis. The chains assemble without directional interactions between them. [Image: see text] |
format | Online Article Text |
id | pubmed-9462186 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-94621862022-11-04 1,4-Bis(4-methoxyphenyl)naphthalene Manickam, R. Jagadeesan, G. Karunakaran, J. Srinivasan, G. IUCrdata Data Reports The title naphthalene derivative, C(24)H(20)O(2), features 4-methyoxy-substituted benzene rings in the 1 and 4 positions of the naphthalene ring system. There are two crystallographically independent molecules (A and B) in asymmetric unit. The independent molecules have very similar conformations in which the naphthalene ring systems are only slightly bent, exhibiting dihedral angles between the constituent benzene rings of 3.76 (15) and 3.39 (15)° for A and B, respectively. The pendent 4-methyoxybenzene rings are splayed out of the plane through the naphthalene ring system to which they are connected [range of dihedral angles = 59.63 (13) to 67.09 (13)°]. In the crystal, the molecular packing is consolidated by intermolecular C—H⋯π interactions, leading to supramolecular chains along the b axis. The chains assemble without directional interactions between them. [Image: see text] International Union of Crystallography 2020-02-21 /pmc/articles/PMC9462186/ /pubmed/36340833 http://dx.doi.org/10.1107/S2414314620002126 Text en © Manickam et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Manickam, R. Jagadeesan, G. Karunakaran, J. Srinivasan, G. 1,4-Bis(4-methoxyphenyl)naphthalene |
title | 1,4-Bis(4-methoxyphenyl)naphthalene |
title_full | 1,4-Bis(4-methoxyphenyl)naphthalene |
title_fullStr | 1,4-Bis(4-methoxyphenyl)naphthalene |
title_full_unstemmed | 1,4-Bis(4-methoxyphenyl)naphthalene |
title_short | 1,4-Bis(4-methoxyphenyl)naphthalene |
title_sort | 1,4-bis(4-methoxyphenyl)naphthalene |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462186/ https://www.ncbi.nlm.nih.gov/pubmed/36340833 http://dx.doi.org/10.1107/S2414314620002126 |
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