Cargando…

1,4-Bis­(4-meth­oxy­phen­yl)naphthalene

The title naphthalene derivative, C(24)H(20)O(2), features 4-methy­oxy-substituted benzene rings in the 1 and 4 positions of the naphthalene ring system. There are two crystallographically independent mol­ecules (A and B) in asymmetric unit. The independent mol­ecules have very similar conformations...

Descripción completa

Detalles Bibliográficos
Autores principales: Manickam, R., Jagadeesan, G., Karunakaran, J., Srinivasan, G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462186/
https://www.ncbi.nlm.nih.gov/pubmed/36340833
http://dx.doi.org/10.1107/S2414314620002126
_version_ 1784787125290401792
author Manickam, R.
Jagadeesan, G.
Karunakaran, J.
Srinivasan, G.
author_facet Manickam, R.
Jagadeesan, G.
Karunakaran, J.
Srinivasan, G.
author_sort Manickam, R.
collection PubMed
description The title naphthalene derivative, C(24)H(20)O(2), features 4-methy­oxy-substituted benzene rings in the 1 and 4 positions of the naphthalene ring system. There are two crystallographically independent mol­ecules (A and B) in asymmetric unit. The independent mol­ecules have very similar conformations in which the naphthalene ring systems are only slightly bent, exhibiting dihedral angles between the constituent benzene rings of 3.76 (15) and 3.39 (15)° for A and B, respectively. The pendent 4-methyoxybenzene rings are splayed out of the plane through the naphthalene ring system to which they are connected [range of dihedral angles = 59.63 (13) to 67.09 (13)°]. In the crystal, the mol­ecular packing is consolidated by inter­molecular C—H⋯π inter­actions, leading to supra­molecular chains along the b axis. The chains assemble without directional inter­actions between them. [Image: see text]
format Online
Article
Text
id pubmed-9462186
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-94621862022-11-04 1,4-Bis­(4-meth­oxy­phen­yl)naphthalene Manickam, R. Jagadeesan, G. Karunakaran, J. Srinivasan, G. IUCrdata Data Reports The title naphthalene derivative, C(24)H(20)O(2), features 4-methy­oxy-substituted benzene rings in the 1 and 4 positions of the naphthalene ring system. There are two crystallographically independent mol­ecules (A and B) in asymmetric unit. The independent mol­ecules have very similar conformations in which the naphthalene ring systems are only slightly bent, exhibiting dihedral angles between the constituent benzene rings of 3.76 (15) and 3.39 (15)° for A and B, respectively. The pendent 4-methyoxybenzene rings are splayed out of the plane through the naphthalene ring system to which they are connected [range of dihedral angles = 59.63 (13) to 67.09 (13)°]. In the crystal, the mol­ecular packing is consolidated by inter­molecular C—H⋯π inter­actions, leading to supra­molecular chains along the b axis. The chains assemble without directional inter­actions between them. [Image: see text] International Union of Crystallography 2020-02-21 /pmc/articles/PMC9462186/ /pubmed/36340833 http://dx.doi.org/10.1107/S2414314620002126 Text en © Manickam et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Manickam, R.
Jagadeesan, G.
Karunakaran, J.
Srinivasan, G.
1,4-Bis­(4-meth­oxy­phen­yl)naphthalene
title 1,4-Bis­(4-meth­oxy­phen­yl)naphthalene
title_full 1,4-Bis­(4-meth­oxy­phen­yl)naphthalene
title_fullStr 1,4-Bis­(4-meth­oxy­phen­yl)naphthalene
title_full_unstemmed 1,4-Bis­(4-meth­oxy­phen­yl)naphthalene
title_short 1,4-Bis­(4-meth­oxy­phen­yl)naphthalene
title_sort 1,4-bis­(4-meth­oxy­phen­yl)naphthalene
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462186/
https://www.ncbi.nlm.nih.gov/pubmed/36340833
http://dx.doi.org/10.1107/S2414314620002126
work_keys_str_mv AT manickamr 14bis4methoxyphenylnaphthalene
AT jagadeesang 14bis4methoxyphenylnaphthalene
AT karunakaranj 14bis4methoxyphenylnaphthalene
AT srinivasang 14bis4methoxyphenylnaphthalene