6-[(tert-Butyl­dimethyl­sil­yl)­oxy]-3-ethenyl-7-meth­oxy-4-[(tri­methyl­sil­yl)ethyn­yl]naphtho­[2,3-c]furan-1(3H)-one

The tricyclic core in the title compound, C(26)H(34)O(4)Si(2), shows disorder of the furan ring and deviates slightly from planarity, with the largest displacement from the least-squares plane [0.166 (2) Å] for the major disordered part of the methine C atom. To this C atom the likewise disordered v...

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Detalles Bibliográficos
Autores principales: Weil, Matthias, Kremsmayr, Thomas, Mihovilovic, Marko D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462189/
https://www.ncbi.nlm.nih.gov/pubmed/36340835
http://dx.doi.org/10.1107/S2414314620002242
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author Weil, Matthias
Kremsmayr, Thomas
Mihovilovic, Marko D.
author_facet Weil, Matthias
Kremsmayr, Thomas
Mihovilovic, Marko D.
author_sort Weil, Matthias
collection PubMed
description The tricyclic core in the title compound, C(26)H(34)O(4)Si(2), shows disorder of the furan ring and deviates slightly from planarity, with the largest displacement from the least-squares plane [0.166 (2) Å] for the major disordered part of the methine C atom. To this C atom the likewise disordered vinyl group is attached, lying nearly perpendicular to the tricyclic core. In the crystal, mutual C—H⋯π inter­actions between the methine group of the furan ring and the central ring of the tricyclic core of an adjacent mol­ecule lead to inversion-related dimers. [Image: see text]
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spelling pubmed-94621892022-11-04 6-[(tert-Butyl­dimethyl­sil­yl)­oxy]-3-ethenyl-7-meth­oxy-4-[(tri­methyl­sil­yl)ethyn­yl]naphtho­[2,3-c]furan-1(3H)-one Weil, Matthias Kremsmayr, Thomas Mihovilovic, Marko D. IUCrdata Data Reports The tricyclic core in the title compound, C(26)H(34)O(4)Si(2), shows disorder of the furan ring and deviates slightly from planarity, with the largest displacement from the least-squares plane [0.166 (2) Å] for the major disordered part of the methine C atom. To this C atom the likewise disordered vinyl group is attached, lying nearly perpendicular to the tricyclic core. In the crystal, mutual C—H⋯π inter­actions between the methine group of the furan ring and the central ring of the tricyclic core of an adjacent mol­ecule lead to inversion-related dimers. [Image: see text] International Union of Crystallography 2020-02-21 /pmc/articles/PMC9462189/ /pubmed/36340835 http://dx.doi.org/10.1107/S2414314620002242 Text en © Weil et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Weil, Matthias
Kremsmayr, Thomas
Mihovilovic, Marko D.
6-[(tert-Butyl­dimethyl­sil­yl)­oxy]-3-ethenyl-7-meth­oxy-4-[(tri­methyl­sil­yl)ethyn­yl]naphtho­[2,3-c]furan-1(3H)-one
title 6-[(tert-Butyl­dimethyl­sil­yl)­oxy]-3-ethenyl-7-meth­oxy-4-[(tri­methyl­sil­yl)ethyn­yl]naphtho­[2,3-c]furan-1(3H)-one
title_full 6-[(tert-Butyl­dimethyl­sil­yl)­oxy]-3-ethenyl-7-meth­oxy-4-[(tri­methyl­sil­yl)ethyn­yl]naphtho­[2,3-c]furan-1(3H)-one
title_fullStr 6-[(tert-Butyl­dimethyl­sil­yl)­oxy]-3-ethenyl-7-meth­oxy-4-[(tri­methyl­sil­yl)ethyn­yl]naphtho­[2,3-c]furan-1(3H)-one
title_full_unstemmed 6-[(tert-Butyl­dimethyl­sil­yl)­oxy]-3-ethenyl-7-meth­oxy-4-[(tri­methyl­sil­yl)ethyn­yl]naphtho­[2,3-c]furan-1(3H)-one
title_short 6-[(tert-Butyl­dimethyl­sil­yl)­oxy]-3-ethenyl-7-meth­oxy-4-[(tri­methyl­sil­yl)ethyn­yl]naphtho­[2,3-c]furan-1(3H)-one
title_sort 6-[(tert-butyl­dimethyl­sil­yl)­oxy]-3-ethenyl-7-meth­oxy-4-[(tri­methyl­sil­yl)ethyn­yl]naphtho­[2,3-c]furan-1(3h)-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462189/
https://www.ncbi.nlm.nih.gov/pubmed/36340835
http://dx.doi.org/10.1107/S2414314620002242
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