12,15-Dimethyl-8-oxa­tetra­cyclo­[8.8.0.0(2,7).0(11,16)]octa­deca-1(18),2,4,6,11(16),12,14-heptaen-10-ol

In the title compound, C(19)H(18)O(2), the pyran ring is in a half-chair conformation. The fused ring system comprising the benzene and cyclo­hexene rings is essentially planar (r.m.s. deviation = 0.053 Å) and forms a dihedral angle of 27.95 (6)° with the other benzene ring. In the crystal, O—H⋯O hy...

Descripción completa

Detalles Bibliográficos
Autores principales: Lough, Alan J., Koh, Samuel, Tam, William
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462194/
https://www.ncbi.nlm.nih.gov/pubmed/36339481
http://dx.doi.org/10.1107/S2414314620003156
_version_ 1784787127488217088
author Lough, Alan J.
Koh, Samuel
Tam, William
author_facet Lough, Alan J.
Koh, Samuel
Tam, William
author_sort Lough, Alan J.
collection PubMed
description In the title compound, C(19)H(18)O(2), the pyran ring is in a half-chair conformation. The fused ring system comprising the benzene and cyclo­hexene rings is essentially planar (r.m.s. deviation = 0.053 Å) and forms a dihedral angle of 27.95 (6)° with the other benzene ring. In the crystal, O—H⋯O hydrogen bonds connect the mol­ecules into chains propagating along [001]. [Image: see text]
format Online
Article
Text
id pubmed-9462194
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-94621942022-11-04 12,15-Dimethyl-8-oxa­tetra­cyclo­[8.8.0.0(2,7).0(11,16)]octa­deca-1(18),2,4,6,11(16),12,14-heptaen-10-ol Lough, Alan J. Koh, Samuel Tam, William IUCrdata Data Reports In the title compound, C(19)H(18)O(2), the pyran ring is in a half-chair conformation. The fused ring system comprising the benzene and cyclo­hexene rings is essentially planar (r.m.s. deviation = 0.053 Å) and forms a dihedral angle of 27.95 (6)° with the other benzene ring. In the crystal, O—H⋯O hydrogen bonds connect the mol­ecules into chains propagating along [001]. [Image: see text] International Union of Crystallography 2020-03-10 /pmc/articles/PMC9462194/ /pubmed/36339481 http://dx.doi.org/10.1107/S2414314620003156 Text en © Lough et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Lough, Alan J.
Koh, Samuel
Tam, William
12,15-Dimethyl-8-oxa­tetra­cyclo­[8.8.0.0(2,7).0(11,16)]octa­deca-1(18),2,4,6,11(16),12,14-heptaen-10-ol
title 12,15-Dimethyl-8-oxa­tetra­cyclo­[8.8.0.0(2,7).0(11,16)]octa­deca-1(18),2,4,6,11(16),12,14-heptaen-10-ol
title_full 12,15-Dimethyl-8-oxa­tetra­cyclo­[8.8.0.0(2,7).0(11,16)]octa­deca-1(18),2,4,6,11(16),12,14-heptaen-10-ol
title_fullStr 12,15-Dimethyl-8-oxa­tetra­cyclo­[8.8.0.0(2,7).0(11,16)]octa­deca-1(18),2,4,6,11(16),12,14-heptaen-10-ol
title_full_unstemmed 12,15-Dimethyl-8-oxa­tetra­cyclo­[8.8.0.0(2,7).0(11,16)]octa­deca-1(18),2,4,6,11(16),12,14-heptaen-10-ol
title_short 12,15-Dimethyl-8-oxa­tetra­cyclo­[8.8.0.0(2,7).0(11,16)]octa­deca-1(18),2,4,6,11(16),12,14-heptaen-10-ol
title_sort 12,15-dimethyl-8-oxa­tetra­cyclo­[8.8.0.0(2,7).0(11,16)]octa­deca-1(18),2,4,6,11(16),12,14-heptaen-10-ol
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462194/
https://www.ncbi.nlm.nih.gov/pubmed/36339481
http://dx.doi.org/10.1107/S2414314620003156
work_keys_str_mv AT loughalanj 1215dimethyl8oxatetracyclo88002701116octadeca11824611161214heptaen10ol
AT kohsamuel 1215dimethyl8oxatetracyclo88002701116octadeca11824611161214heptaen10ol
AT tamwilliam 1215dimethyl8oxatetracyclo88002701116octadeca11824611161214heptaen10ol

Ejemplares similares