Trimethyl 4,4′,4′′-(ethene-1,1,2-tri­yl)tribenzoate

The title compound, C(26)H(22)O(6), is formed as the major product from the reaction between syn-1,2-bis­(pinacolatoboron)-1,2-bis­(4-methyl­carb­oxy­phen­yl)ethene and excess methyl 4-iodo­benzoate in basic DMSO using a palladium catalyst at 80°C via Suzuki coupling followed by protodeboronation. C...

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Detalles Bibliográficos
Autores principales: Lesley, Melvin J. G., Ozhan, Koray, Sung, Herman H.-Y., Williams, Ian D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462201/
https://www.ncbi.nlm.nih.gov/pubmed/36339477
http://dx.doi.org/10.1107/S2414314620004174
Descripción
Sumario:The title compound, C(26)H(22)O(6), is formed as the major product from the reaction between syn-1,2-bis­(pinacolatoboron)-1,2-bis­(4-methyl­carb­oxy­phen­yl)ethene and excess methyl 4-iodo­benzoate in basic DMSO using a palladium catalyst at 80°C via Suzuki coupling followed by protodeboronation. Crystals were grown by slow evaporation of a hexa­nes solution at room temperature. [Image: see text]

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