Trimethyl 4,4′,4′′-(ethene-1,1,2-tri­yl)tribenzoate

The title compound, C(26)H(22)O(6), is formed as the major product from the reaction between syn-1,2-bis­(pinacolatoboron)-1,2-bis­(4-methyl­carb­oxy­phen­yl)ethene and excess methyl 4-iodo­benzoate in basic DMSO using a palladium catalyst at 80°C via Suzuki coupling followed by protodeboronation. C...

Descripción completa

Detalles Bibliográficos
Autores principales: Lesley, Melvin J. G., Ozhan, Koray, Sung, Herman H.-Y., Williams, Ian D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462201/
https://www.ncbi.nlm.nih.gov/pubmed/36339477
http://dx.doi.org/10.1107/S2414314620004174
_version_ 1784787129763627008
author Lesley, Melvin J. G.
Ozhan, Koray
Sung, Herman H.-Y.
Williams, Ian D.
author_facet Lesley, Melvin J. G.
Ozhan, Koray
Sung, Herman H.-Y.
Williams, Ian D.
author_sort Lesley, Melvin J. G.
collection PubMed
description The title compound, C(26)H(22)O(6), is formed as the major product from the reaction between syn-1,2-bis­(pinacolatoboron)-1,2-bis­(4-methyl­carb­oxy­phen­yl)ethene and excess methyl 4-iodo­benzoate in basic DMSO using a palladium catalyst at 80°C via Suzuki coupling followed by protodeboronation. Crystals were grown by slow evaporation of a hexa­nes solution at room temperature. [Image: see text]
format Online
Article
Text
id pubmed-9462201
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-94622012022-11-04 Trimethyl 4,4′,4′′-(ethene-1,1,2-tri­yl)tribenzoate Lesley, Melvin J. G. Ozhan, Koray Sung, Herman H.-Y. Williams, Ian D. IUCrdata Data Reports The title compound, C(26)H(22)O(6), is formed as the major product from the reaction between syn-1,2-bis­(pinacolatoboron)-1,2-bis­(4-methyl­carb­oxy­phen­yl)ethene and excess methyl 4-iodo­benzoate in basic DMSO using a palladium catalyst at 80°C via Suzuki coupling followed by protodeboronation. Crystals were grown by slow evaporation of a hexa­nes solution at room temperature. [Image: see text] International Union of Crystallography 2020-03-31 /pmc/articles/PMC9462201/ /pubmed/36339477 http://dx.doi.org/10.1107/S2414314620004174 Text en © Lesley et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Lesley, Melvin J. G.
Ozhan, Koray
Sung, Herman H.-Y.
Williams, Ian D.
Trimethyl 4,4′,4′′-(ethene-1,1,2-tri­yl)tribenzoate
title Trimethyl 4,4′,4′′-(ethene-1,1,2-tri­yl)tribenzoate
title_full Trimethyl 4,4′,4′′-(ethene-1,1,2-tri­yl)tribenzoate
title_fullStr Trimethyl 4,4′,4′′-(ethene-1,1,2-tri­yl)tribenzoate
title_full_unstemmed Trimethyl 4,4′,4′′-(ethene-1,1,2-tri­yl)tribenzoate
title_short Trimethyl 4,4′,4′′-(ethene-1,1,2-tri­yl)tribenzoate
title_sort trimethyl 4,4′,4′′-(ethene-1,1,2-tri­yl)tribenzoate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462201/
https://www.ncbi.nlm.nih.gov/pubmed/36339477
http://dx.doi.org/10.1107/S2414314620004174
work_keys_str_mv AT lesleymelvinjg trimethyl444ethene112triyltribenzoate
AT ozhankoray trimethyl444ethene112triyltribenzoate
AT sunghermanhy trimethyl444ethene112triyltribenzoate
AT williamsiand trimethyl444ethene112triyltribenzoate

Ejemplares similares