6,7-Di­hydro-5H-pyrrolo­[1,2-a]imidazole

The crystal structure of 6,7-di­hydro-5H-pyrrolo­[1,2-a]imidazole, C(6)H(8)N(2), at 100 K has monoclinic (P2(1)/n) symmetry. The mol­ecule adopts an envelope conformation of the pyrrolidine ring, which might help for the relief torsion tension. The crystal cohesion is achieved by C—H⋯N hydrogen bond...

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Detalles Bibliográficos
Autores principales: Morales-Collazo, Oscar, Lynch, Vincent M., Brennecke, Joan F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462221/
https://www.ncbi.nlm.nih.gov/pubmed/36337149
http://dx.doi.org/10.1107/S2414314620006811
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author Morales-Collazo, Oscar
Lynch, Vincent M.
Brennecke, Joan F.
author_facet Morales-Collazo, Oscar
Lynch, Vincent M.
Brennecke, Joan F.
author_sort Morales-Collazo, Oscar
collection PubMed
description The crystal structure of 6,7-di­hydro-5H-pyrrolo­[1,2-a]imidazole, C(6)H(8)N(2), at 100 K has monoclinic (P2(1)/n) symmetry. The mol­ecule adopts an envelope conformation of the pyrrolidine ring, which might help for the relief torsion tension. The crystal cohesion is achieved by C—H⋯N hydrogen bonds. Inter­estingly, this fused ring system provides protection of the α-C atom (attached to the non-bridging N atom of the imidazole ring), which provides stability that is of inter­est with respect to electrochemical properties as electrolytes for fuel cells and batteries, and electrodeposition. [Image: see text]
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spelling pubmed-94622212022-11-04 6,7-Di­hydro-5H-pyrrolo­[1,2-a]imidazole Morales-Collazo, Oscar Lynch, Vincent M. Brennecke, Joan F. IUCrdata Data Reports The crystal structure of 6,7-di­hydro-5H-pyrrolo­[1,2-a]imidazole, C(6)H(8)N(2), at 100 K has monoclinic (P2(1)/n) symmetry. The mol­ecule adopts an envelope conformation of the pyrrolidine ring, which might help for the relief torsion tension. The crystal cohesion is achieved by C—H⋯N hydrogen bonds. Inter­estingly, this fused ring system provides protection of the α-C atom (attached to the non-bridging N atom of the imidazole ring), which provides stability that is of inter­est with respect to electrochemical properties as electrolytes for fuel cells and batteries, and electrodeposition. [Image: see text] International Union of Crystallography 2020-05-29 /pmc/articles/PMC9462221/ /pubmed/36337149 http://dx.doi.org/10.1107/S2414314620006811 Text en © Morales-Collazo et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Morales-Collazo, Oscar
Lynch, Vincent M.
Brennecke, Joan F.
6,7-Di­hydro-5H-pyrrolo­[1,2-a]imidazole
title 6,7-Di­hydro-5H-pyrrolo­[1,2-a]imidazole
title_full 6,7-Di­hydro-5H-pyrrolo­[1,2-a]imidazole
title_fullStr 6,7-Di­hydro-5H-pyrrolo­[1,2-a]imidazole
title_full_unstemmed 6,7-Di­hydro-5H-pyrrolo­[1,2-a]imidazole
title_short 6,7-Di­hydro-5H-pyrrolo­[1,2-a]imidazole
title_sort 6,7-di­hydro-5h-pyrrolo­[1,2-a]imidazole
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462221/
https://www.ncbi.nlm.nih.gov/pubmed/36337149
http://dx.doi.org/10.1107/S2414314620006811
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