Tris(ethane-1,2-di­amine-κ(2) N,N′)zinc(II) tetra­chlorido­zincate(II)

The title complex, [Zn(C(2)H(8)N(2))(3)][ZnCl(4)], exists as discrete ions. The [Zn(C(2)H(8)N(2))(3)](2+) cation exhibits a distorted octa­hedral shape. In the [ZnCl(4)](2−) anion, the Zn(II) atom is in an almost regular tetra­hedral environment. The crystal packing is consolidated by N—H⋯Cl and C—H...

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Detalles Bibliográficos
Autores principales: AaminaNaaz, Y., Rajkumar, K., Thirumurugan, S., Anbalagan, K., SubbiahPandi, A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462225/
https://www.ncbi.nlm.nih.gov/pubmed/36337145
http://dx.doi.org/10.1107/S2414314620006185
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author AaminaNaaz, Y.
Rajkumar, K.
Thirumurugan, S.
Anbalagan, K.
SubbiahPandi, A.
author_facet AaminaNaaz, Y.
Rajkumar, K.
Thirumurugan, S.
Anbalagan, K.
SubbiahPandi, A.
author_sort AaminaNaaz, Y.
collection PubMed
description The title complex, [Zn(C(2)H(8)N(2))(3)][ZnCl(4)], exists as discrete ions. The [Zn(C(2)H(8)N(2))(3)](2+) cation exhibits a distorted octa­hedral shape. In the [ZnCl(4)](2−) anion, the Zn(II) atom is in an almost regular tetra­hedral environment. The crystal packing is consolidated by N—H⋯Cl and C—H⋯Cl hydrogen bonds. [Image: see text]
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spelling pubmed-94622252022-11-04 Tris(ethane-1,2-di­amine-κ(2) N,N′)zinc(II) tetra­chlorido­zincate(II) AaminaNaaz, Y. Rajkumar, K. Thirumurugan, S. Anbalagan, K. SubbiahPandi, A. IUCrdata Data Reports The title complex, [Zn(C(2)H(8)N(2))(3)][ZnCl(4)], exists as discrete ions. The [Zn(C(2)H(8)N(2))(3)](2+) cation exhibits a distorted octa­hedral shape. In the [ZnCl(4)](2−) anion, the Zn(II) atom is in an almost regular tetra­hedral environment. The crystal packing is consolidated by N—H⋯Cl and C—H⋯Cl hydrogen bonds. [Image: see text] International Union of Crystallography 2020-05-12 /pmc/articles/PMC9462225/ /pubmed/36337145 http://dx.doi.org/10.1107/S2414314620006185 Text en © AaminaNaaz et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
AaminaNaaz, Y.
Rajkumar, K.
Thirumurugan, S.
Anbalagan, K.
SubbiahPandi, A.
Tris(ethane-1,2-di­amine-κ(2) N,N′)zinc(II) tetra­chlorido­zincate(II)
title Tris(ethane-1,2-di­amine-κ(2) N,N′)zinc(II) tetra­chlorido­zincate(II)
title_full Tris(ethane-1,2-di­amine-κ(2) N,N′)zinc(II) tetra­chlorido­zincate(II)
title_fullStr Tris(ethane-1,2-di­amine-κ(2) N,N′)zinc(II) tetra­chlorido­zincate(II)
title_full_unstemmed Tris(ethane-1,2-di­amine-κ(2) N,N′)zinc(II) tetra­chlorido­zincate(II)
title_short Tris(ethane-1,2-di­amine-κ(2) N,N′)zinc(II) tetra­chlorido­zincate(II)
title_sort tris(ethane-1,2-di­amine-κ(2) n,n′)zinc(ii) tetra­chlorido­zincate(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462225/
https://www.ncbi.nlm.nih.gov/pubmed/36337145
http://dx.doi.org/10.1107/S2414314620006185
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