1-Benzyl-3-methyl­imidazolium bromide

The title compound, (BenzMIm)Br (BenzMIm=1-benzyl-3-methyl­imidazo­l­ium), C(11)H(13)N(2) (+)·Br(−), was obtained as single crystals directly from a pure and liquid sample of the compound over several weeks. The mol­ecular structure of (BenzMIm)Br consists of separated bromide anions and 1-benzyl-3-...

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Detalles Bibliográficos
Autores principales: Peppel, Tim, Wulf, Christoph, Spannenberg, Anke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462234/
https://www.ncbi.nlm.nih.gov/pubmed/36340612
http://dx.doi.org/10.1107/S2414314620007683
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author Peppel, Tim
Wulf, Christoph
Spannenberg, Anke
author_facet Peppel, Tim
Wulf, Christoph
Spannenberg, Anke
author_sort Peppel, Tim
collection PubMed
description The title compound, (BenzMIm)Br (BenzMIm=1-benzyl-3-methyl­imidazo­l­ium), C(11)H(13)N(2) (+)·Br(−), was obtained as single crystals directly from a pure and liquid sample of the compound over several weeks. The mol­ecular structure of (BenzMIm)Br consists of separated bromide anions and 1-benzyl-3-methyl­imidazolium cations connected via short C—H⋯Br contacts. The compound exhibits a relatively low melting point (m.p. = 72°C) and is a supercooled, highly viscous transparent liquid at ambient conditions. The title compound crystallizes with two unique ion pairs in the asymmetric unit of the orthorhombic unit cell. [Image: see text]
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spelling pubmed-94622342022-11-04 1-Benzyl-3-methyl­imidazolium bromide Peppel, Tim Wulf, Christoph Spannenberg, Anke IUCrdata Data Reports The title compound, (BenzMIm)Br (BenzMIm=1-benzyl-3-methyl­imidazo­l­ium), C(11)H(13)N(2) (+)·Br(−), was obtained as single crystals directly from a pure and liquid sample of the compound over several weeks. The mol­ecular structure of (BenzMIm)Br consists of separated bromide anions and 1-benzyl-3-methyl­imidazolium cations connected via short C—H⋯Br contacts. The compound exhibits a relatively low melting point (m.p. = 72°C) and is a supercooled, highly viscous transparent liquid at ambient conditions. The title compound crystallizes with two unique ion pairs in the asymmetric unit of the orthorhombic unit cell. [Image: see text] International Union of Crystallography 2020-06-09 /pmc/articles/PMC9462234/ /pubmed/36340612 http://dx.doi.org/10.1107/S2414314620007683 Text en © Peppel et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Peppel, Tim
Wulf, Christoph
Spannenberg, Anke
1-Benzyl-3-methyl­imidazolium bromide
title 1-Benzyl-3-methyl­imidazolium bromide
title_full 1-Benzyl-3-methyl­imidazolium bromide
title_fullStr 1-Benzyl-3-methyl­imidazolium bromide
title_full_unstemmed 1-Benzyl-3-methyl­imidazolium bromide
title_short 1-Benzyl-3-methyl­imidazolium bromide
title_sort 1-benzyl-3-methyl­imidazolium bromide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462234/
https://www.ncbi.nlm.nih.gov/pubmed/36340612
http://dx.doi.org/10.1107/S2414314620007683
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AT wulfchristoph 1benzyl3methylimidazoliumbromide
AT spannenberganke 1benzyl3methylimidazoliumbromide

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