Di-μ-aqua-bis­[aqua­(2,2′-bi­pyridine)(4-nitro­benzoato)cobalt(II)] bis­(4-nitro­benzoate)

The title compound, [Co(2)(C(7)H(4)NO(4))(2)(C(10)H(8)N(2))(2)(H(2)O)(4)](C(7)H(4)NO(4))(2), consists of a centrosymmetric bimetallic complex charge-balanced by free 4-nitro­benzoate anions. The Co(II) ion exhibits a distorted cis-CoN(2)O(4) octa­hedral coordination environment and the Co⋯Co separat...

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Detalles Bibliográficos
Autores principales: Srinivasan, Bikshandarkoil R., Harmalkar, Sarvesh S., D’Souza, Luann R., Dhuri, Sunder N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462235/
https://www.ncbi.nlm.nih.gov/pubmed/36340610
http://dx.doi.org/10.1107/S2414314620007968
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author Srinivasan, Bikshandarkoil R.
Harmalkar, Sarvesh S.
D’Souza, Luann R.
Dhuri, Sunder N.
author_facet Srinivasan, Bikshandarkoil R.
Harmalkar, Sarvesh S.
D’Souza, Luann R.
Dhuri, Sunder N.
author_sort Srinivasan, Bikshandarkoil R.
collection PubMed
description The title compound, [Co(2)(C(7)H(4)NO(4))(2)(C(10)H(8)N(2))(2)(H(2)O)(4)](C(7)H(4)NO(4))(2), consists of a centrosymmetric bimetallic complex charge-balanced by free 4-nitro­benzoate anions. The Co(II) ion exhibits a distorted cis-CoN(2)O(4) octa­hedral coordination environment and the Co⋯Co separation is 3.326 (2) Å. In the crystal, the dications and anions are linked by O—H⋯O and C—H⋯O hydrogen bonds. [Image: see text]
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spelling pubmed-94622352022-11-04 Di-μ-aqua-bis­[aqua­(2,2′-bi­pyridine)(4-nitro­benzoato)cobalt(II)] bis­(4-nitro­benzoate) Srinivasan, Bikshandarkoil R. Harmalkar, Sarvesh S. D’Souza, Luann R. Dhuri, Sunder N. IUCrdata Data Reports The title compound, [Co(2)(C(7)H(4)NO(4))(2)(C(10)H(8)N(2))(2)(H(2)O)(4)](C(7)H(4)NO(4))(2), consists of a centrosymmetric bimetallic complex charge-balanced by free 4-nitro­benzoate anions. The Co(II) ion exhibits a distorted cis-CoN(2)O(4) octa­hedral coordination environment and the Co⋯Co separation is 3.326 (2) Å. In the crystal, the dications and anions are linked by O—H⋯O and C—H⋯O hydrogen bonds. [Image: see text] International Union of Crystallography 2020-06-19 /pmc/articles/PMC9462235/ /pubmed/36340610 http://dx.doi.org/10.1107/S2414314620007968 Text en © Srinivasan et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Srinivasan, Bikshandarkoil R.
Harmalkar, Sarvesh S.
D’Souza, Luann R.
Dhuri, Sunder N.
Di-μ-aqua-bis­[aqua­(2,2′-bi­pyridine)(4-nitro­benzoato)cobalt(II)] bis­(4-nitro­benzoate)
title Di-μ-aqua-bis­[aqua­(2,2′-bi­pyridine)(4-nitro­benzoato)cobalt(II)] bis­(4-nitro­benzoate)
title_full Di-μ-aqua-bis­[aqua­(2,2′-bi­pyridine)(4-nitro­benzoato)cobalt(II)] bis­(4-nitro­benzoate)
title_fullStr Di-μ-aqua-bis­[aqua­(2,2′-bi­pyridine)(4-nitro­benzoato)cobalt(II)] bis­(4-nitro­benzoate)
title_full_unstemmed Di-μ-aqua-bis­[aqua­(2,2′-bi­pyridine)(4-nitro­benzoato)cobalt(II)] bis­(4-nitro­benzoate)
title_short Di-μ-aqua-bis­[aqua­(2,2′-bi­pyridine)(4-nitro­benzoato)cobalt(II)] bis­(4-nitro­benzoate)
title_sort di-μ-aqua-bis­[aqua­(2,2′-bi­pyridine)(4-nitro­benzoato)cobalt(ii)] bis­(4-nitro­benzoate)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462235/
https://www.ncbi.nlm.nih.gov/pubmed/36340610
http://dx.doi.org/10.1107/S2414314620007968
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