[1,3-Bis(2,6-diiso­propyl­phen­yl)-1,3-di­hydro-2H-imidazol-2-yl­idene]tri­iodo­borane benzene hemisolvate

In the title hemisolvate, C(27)H(36)BI(3)N(2) (.)0.5C(6)H(6), the dihedral angles between the central heterocyclic ring and pendant benzene rings are 82.9 (8) and 88.7 (9)° and the complete benzene solvent mol­ecule of crystallization is generated by a crystallographic centre of inversion. In the cr...

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Detalles Bibliográficos
Autores principales: Schödel, Frauke, Lerner, Hans-Wolfram, Bolte, Michael
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462236/
https://www.ncbi.nlm.nih.gov/pubmed/36340616
http://dx.doi.org/10.1107/S2414314620008639
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author Schödel, Frauke
Lerner, Hans-Wolfram
Bolte, Michael
author_facet Schödel, Frauke
Lerner, Hans-Wolfram
Bolte, Michael
author_sort Schödel, Frauke
collection PubMed
description In the title hemisolvate, C(27)H(36)BI(3)N(2) (.)0.5C(6)H(6), the dihedral angles between the central heterocyclic ring and pendant benzene rings are 82.9 (8) and 88.7 (9)° and the complete benzene solvent mol­ecule of crystallization is generated by a crystallographic centre of inversion. In the crystal, one very weak C—H⋯I inter­action links the mol­ecules into [001] chains. [Image: see text]
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spelling pubmed-94622362022-11-04 [1,3-Bis(2,6-diiso­propyl­phen­yl)-1,3-di­hydro-2H-imidazol-2-yl­idene]tri­iodo­borane benzene hemisolvate Schödel, Frauke Lerner, Hans-Wolfram Bolte, Michael IUCrdata Data Reports In the title hemisolvate, C(27)H(36)BI(3)N(2) (.)0.5C(6)H(6), the dihedral angles between the central heterocyclic ring and pendant benzene rings are 82.9 (8) and 88.7 (9)° and the complete benzene solvent mol­ecule of crystallization is generated by a crystallographic centre of inversion. In the crystal, one very weak C—H⋯I inter­action links the mol­ecules into [001] chains. [Image: see text] International Union of Crystallography 2020-06-30 /pmc/articles/PMC9462236/ /pubmed/36340616 http://dx.doi.org/10.1107/S2414314620008639 Text en © Schödel et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Schödel, Frauke
Lerner, Hans-Wolfram
Bolte, Michael
[1,3-Bis(2,6-diiso­propyl­phen­yl)-1,3-di­hydro-2H-imidazol-2-yl­idene]tri­iodo­borane benzene hemisolvate
title [1,3-Bis(2,6-diiso­propyl­phen­yl)-1,3-di­hydro-2H-imidazol-2-yl­idene]tri­iodo­borane benzene hemisolvate
title_full [1,3-Bis(2,6-diiso­propyl­phen­yl)-1,3-di­hydro-2H-imidazol-2-yl­idene]tri­iodo­borane benzene hemisolvate
title_fullStr [1,3-Bis(2,6-diiso­propyl­phen­yl)-1,3-di­hydro-2H-imidazol-2-yl­idene]tri­iodo­borane benzene hemisolvate
title_full_unstemmed [1,3-Bis(2,6-diiso­propyl­phen­yl)-1,3-di­hydro-2H-imidazol-2-yl­idene]tri­iodo­borane benzene hemisolvate
title_short [1,3-Bis(2,6-diiso­propyl­phen­yl)-1,3-di­hydro-2H-imidazol-2-yl­idene]tri­iodo­borane benzene hemisolvate
title_sort [1,3-bis(2,6-diiso­propyl­phen­yl)-1,3-di­hydro-2h-imidazol-2-yl­idene]tri­iodo­borane benzene hemisolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462236/
https://www.ncbi.nlm.nih.gov/pubmed/36340616
http://dx.doi.org/10.1107/S2414314620008639
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