[2,2′-Bis(di­phenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]di­chlorido­platinum(II) acetonitrile trisolvate

The crystal structure (150 K) of the racemic title compound, [PtCl(2)(C(44)H(32)P(2))]·3CH(3)CN, has been determined. The asymmetric unit comprises a single mol­ecule of the title compound co-crystallized with three aceto­nitrile solvent mol­ecules. Four mol­ecules are observed in the unit cell, wit...

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Detalles Bibliográficos
Autores principales: Braun, Jason D., Uppal, Guneet, Herbert, David E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462241/
https://www.ncbi.nlm.nih.gov/pubmed/36338509
http://dx.doi.org/10.1107/S2414314620010482
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author Braun, Jason D.
Uppal, Guneet
Herbert, David E.
author_facet Braun, Jason D.
Uppal, Guneet
Herbert, David E.
author_sort Braun, Jason D.
collection PubMed
description The crystal structure (150 K) of the racemic title compound, [PtCl(2)(C(44)H(32)P(2))]·3CH(3)CN, has been determined. The asymmetric unit comprises a single mol­ecule of the title compound co-crystallized with three aceto­nitrile solvent mol­ecules. Four mol­ecules are observed in the unit cell, with R and S enanti­omers present in a 2:2 ratio. Evidence of intra­molecular π-stacking is observed with no discernable inter­molecular inter­actions. [Image: see text]
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spelling pubmed-94622412022-11-04 [2,2′-Bis(di­phenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]di­chlorido­platinum(II) acetonitrile trisolvate Braun, Jason D. Uppal, Guneet Herbert, David E. IUCrdata Data Reports The crystal structure (150 K) of the racemic title compound, [PtCl(2)(C(44)H(32)P(2))]·3CH(3)CN, has been determined. The asymmetric unit comprises a single mol­ecule of the title compound co-crystallized with three aceto­nitrile solvent mol­ecules. Four mol­ecules are observed in the unit cell, with R and S enanti­omers present in a 2:2 ratio. Evidence of intra­molecular π-stacking is observed with no discernable inter­molecular inter­actions. [Image: see text] International Union of Crystallography 2020-08-04 /pmc/articles/PMC9462241/ /pubmed/36338509 http://dx.doi.org/10.1107/S2414314620010482 Text en © Herbert et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Braun, Jason D.
Uppal, Guneet
Herbert, David E.
[2,2′-Bis(di­phenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]di­chlorido­platinum(II) acetonitrile trisolvate
title [2,2′-Bis(di­phenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]di­chlorido­platinum(II) acetonitrile trisolvate
title_full [2,2′-Bis(di­phenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]di­chlorido­platinum(II) acetonitrile trisolvate
title_fullStr [2,2′-Bis(di­phenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]di­chlorido­platinum(II) acetonitrile trisolvate
title_full_unstemmed [2,2′-Bis(di­phenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]di­chlorido­platinum(II) acetonitrile trisolvate
title_short [2,2′-Bis(di­phenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) P,P′]di­chlorido­platinum(II) acetonitrile trisolvate
title_sort [2,2′-bis(di­phenyl­phosphan­yl)-1,1′-binaphthyl-κ(2) p,p′]di­chlorido­platinum(ii) acetonitrile trisolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462241/
https://www.ncbi.nlm.nih.gov/pubmed/36338509
http://dx.doi.org/10.1107/S2414314620010482
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AT herbertdavide 22bisdiphenylphosphanyl11binaphthylk2ppdichloridoplatinumiiacetonitriletrisolvate

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