trans-Diamminebis(1,2-di­cyano­ethene-1,2-di­thiol­ato)platinum(IV)

The title compound, [Pt(C(4)N(2)S(2))(2)(NH(3))(2)], represents an octa­hedral platinum(IV) complex with two trans-ammine and two mnt (mnt = 1,2-di­cyano­ethene-1,2-di­thiol­ato) ligands. The Pt—N and Pt—S distances are consistent with those in other platinum(IV) complexes. As a result of a slight c...

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Autores principales: Siddiqui, Mahaa J., Nesterov, Volodymyr V., Steidle, Matthew T., Smucker, Bradley W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462246/
https://www.ncbi.nlm.nih.gov/pubmed/36339788
http://dx.doi.org/10.1107/S2414314620009803
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author Siddiqui, Mahaa J.
Nesterov, Volodymyr V.
Steidle, Matthew T.
Smucker, Bradley W.
author_facet Siddiqui, Mahaa J.
Nesterov, Volodymyr V.
Steidle, Matthew T.
Smucker, Bradley W.
author_sort Siddiqui, Mahaa J.
collection PubMed
description The title compound, [Pt(C(4)N(2)S(2))(2)(NH(3))(2)], represents an octa­hedral platinum(IV) complex with two trans-ammine and two mnt (mnt = 1,2-di­cyano­ethene-1,2-di­thiol­ato) ligands. The Pt—N and Pt—S distances are consistent with those in other platinum(IV) complexes. As a result of a slight canting of the coordination of the mnt ligand to the platinum(IV) atom, the nitrile nitro­gen atoms are positioned suitably to hydrogen-bond with adjacent ammines. [Image: see text]
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spelling pubmed-94622462022-11-04 trans-Diamminebis(1,2-di­cyano­ethene-1,2-di­thiol­ato)platinum(IV) Siddiqui, Mahaa J. Nesterov, Volodymyr V. Steidle, Matthew T. Smucker, Bradley W. IUCrdata Data Reports The title compound, [Pt(C(4)N(2)S(2))(2)(NH(3))(2)], represents an octa­hedral platinum(IV) complex with two trans-ammine and two mnt (mnt = 1,2-di­cyano­ethene-1,2-di­thiol­ato) ligands. The Pt—N and Pt—S distances are consistent with those in other platinum(IV) complexes. As a result of a slight canting of the coordination of the mnt ligand to the platinum(IV) atom, the nitrile nitro­gen atoms are positioned suitably to hydrogen-bond with adjacent ammines. [Image: see text] International Union of Crystallography 2020-07-28 /pmc/articles/PMC9462246/ /pubmed/36339788 http://dx.doi.org/10.1107/S2414314620009803 Text en © Siddiqui et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Siddiqui, Mahaa J.
Nesterov, Volodymyr V.
Steidle, Matthew T.
Smucker, Bradley W.
trans-Diamminebis(1,2-di­cyano­ethene-1,2-di­thiol­ato)platinum(IV)
title trans-Diamminebis(1,2-di­cyano­ethene-1,2-di­thiol­ato)platinum(IV)
title_full trans-Diamminebis(1,2-di­cyano­ethene-1,2-di­thiol­ato)platinum(IV)
title_fullStr trans-Diamminebis(1,2-di­cyano­ethene-1,2-di­thiol­ato)platinum(IV)
title_full_unstemmed trans-Diamminebis(1,2-di­cyano­ethene-1,2-di­thiol­ato)platinum(IV)
title_short trans-Diamminebis(1,2-di­cyano­ethene-1,2-di­thiol­ato)platinum(IV)
title_sort trans-diamminebis(1,2-di­cyano­ethene-1,2-di­thiol­ato)platinum(iv)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462246/
https://www.ncbi.nlm.nih.gov/pubmed/36339788
http://dx.doi.org/10.1107/S2414314620009803
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