Rerefinement of the crystal structure of tri­chlorido­sulfonium­(IV) hexa­chlorido­uranate(V), (SCl(3))[UCl(6)]

Single crystals of tri­chlorido­sulfonium­(IV) hexa­chlorido­uranate(V) were obtained from the reaction of uranium(IV) chloride with an excess of disulfur dichloride and studied by single-crystal X-ray diffraction. In comparison with the structure model reported previously [Sawodny et al. (1983 ▸)....

Descripción completa

Detalles Bibliográficos
Autores principales: Deubner, Holger Lars, Ivlev, Sergei I., Kraus, Florian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462248/
https://www.ncbi.nlm.nih.gov/pubmed/36339779
http://dx.doi.org/10.1107/S2414314620009608
Descripción
Sumario:Single crystals of tri­chlorido­sulfonium­(IV) hexa­chlorido­uranate(V) were obtained from the reaction of uranium(IV) chloride with an excess of disulfur dichloride and studied by single-crystal X-ray diffraction. In comparison with the structure model reported previously [Sawodny et al. (1983 ▸). Z. Anorg. Allg. Chem. 499, 81–88.], the lattice parameters and fractional atomic coordinates were determined to a much higher precision, leading overall to an improved structure model. The ionic compound contains trigonal–pyramidal (SCl(3))(+) cations and slightly distorted octa­hedral [UCl(6)](−) anions. The structure was refined as an inversion twin with a twin ratio of 4.4:1. [Image: see text]

Ejemplares similares