Rerefinement of the crystal structure of tri­chlorido­sulfonium­(IV) hexa­chlorido­uranate(V), (SCl(3))[UCl(6)]

Single crystals of tri­chlorido­sulfonium­(IV) hexa­chlorido­uranate(V) were obtained from the reaction of uranium(IV) chloride with an excess of disulfur dichloride and studied by single-crystal X-ray diffraction. In comparison with the structure model reported previously [Sawodny et al. (1983 ▸)....

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Autores principales: Deubner, Holger Lars, Ivlev, Sergei I., Kraus, Florian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462248/
https://www.ncbi.nlm.nih.gov/pubmed/36339779
http://dx.doi.org/10.1107/S2414314620009608
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author Deubner, Holger Lars
Ivlev, Sergei I.
Kraus, Florian
author_facet Deubner, Holger Lars
Ivlev, Sergei I.
Kraus, Florian
author_sort Deubner, Holger Lars
collection PubMed
description Single crystals of tri­chlorido­sulfonium­(IV) hexa­chlorido­uranate(V) were obtained from the reaction of uranium(IV) chloride with an excess of disulfur dichloride and studied by single-crystal X-ray diffraction. In comparison with the structure model reported previously [Sawodny et al. (1983 ▸). Z. Anorg. Allg. Chem. 499, 81–88.], the lattice parameters and fractional atomic coordinates were determined to a much higher precision, leading overall to an improved structure model. The ionic compound contains trigonal–pyramidal (SCl(3))(+) cations and slightly distorted octa­hedral [UCl(6)](−) anions. The structure was refined as an inversion twin with a twin ratio of 4.4:1. [Image: see text]
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spelling pubmed-94622482022-11-04 Rerefinement of the crystal structure of tri­chlorido­sulfonium­(IV) hexa­chlorido­uranate(V), (SCl(3))[UCl(6)] Deubner, Holger Lars Ivlev, Sergei I. Kraus, Florian IUCrdata Data Reports Single crystals of tri­chlorido­sulfonium­(IV) hexa­chlorido­uranate(V) were obtained from the reaction of uranium(IV) chloride with an excess of disulfur dichloride and studied by single-crystal X-ray diffraction. In comparison with the structure model reported previously [Sawodny et al. (1983 ▸). Z. Anorg. Allg. Chem. 499, 81–88.], the lattice parameters and fractional atomic coordinates were determined to a much higher precision, leading overall to an improved structure model. The ionic compound contains trigonal–pyramidal (SCl(3))(+) cations and slightly distorted octa­hedral [UCl(6)](−) anions. The structure was refined as an inversion twin with a twin ratio of 4.4:1. [Image: see text] International Union of Crystallography 2020-07-17 /pmc/articles/PMC9462248/ /pubmed/36339779 http://dx.doi.org/10.1107/S2414314620009608 Text en © Deubner et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Deubner, Holger Lars
Ivlev, Sergei I.
Kraus, Florian
Rerefinement of the crystal structure of tri­chlorido­sulfonium­(IV) hexa­chlorido­uranate(V), (SCl(3))[UCl(6)]
title Rerefinement of the crystal structure of tri­chlorido­sulfonium­(IV) hexa­chlorido­uranate(V), (SCl(3))[UCl(6)]
title_full Rerefinement of the crystal structure of tri­chlorido­sulfonium­(IV) hexa­chlorido­uranate(V), (SCl(3))[UCl(6)]
title_fullStr Rerefinement of the crystal structure of tri­chlorido­sulfonium­(IV) hexa­chlorido­uranate(V), (SCl(3))[UCl(6)]
title_full_unstemmed Rerefinement of the crystal structure of tri­chlorido­sulfonium­(IV) hexa­chlorido­uranate(V), (SCl(3))[UCl(6)]
title_short Rerefinement of the crystal structure of tri­chlorido­sulfonium­(IV) hexa­chlorido­uranate(V), (SCl(3))[UCl(6)]
title_sort rerefinement of the crystal structure of tri­chlorido­sulfonium­(iv) hexa­chlorido­uranate(v), (scl(3))[ucl(6)]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462248/
https://www.ncbi.nlm.nih.gov/pubmed/36339779
http://dx.doi.org/10.1107/S2414314620009608
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