(Z)-5-(4-Bromo­phen­yl)-3-{[(3,5-di­chloro­phen­yl)amino]­methyl­idene}furan-2(3H)-one

The title compound, C(17)H(10)BrCl(2)NO(2), crystallizes in the monoclinic space group C2/c with a large cell volume of 6207 (3) Å(3). The asymmetric unit of the title compound investigated at 120 K contains two crystallographically independent mol­ecules (Z′ = 2). Each mol­ecule demonstrates slight...

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Detalles Bibliográficos
Autores principales: Mayorova, Oksana A., Grinev, Vyacheslav S., Yegorova, Alevtina Yu.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462252/
https://www.ncbi.nlm.nih.gov/pubmed/36339791
http://dx.doi.org/10.1107/S2414314620009372
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author Mayorova, Oksana A.
Grinev, Vyacheslav S.
Yegorova, Alevtina Yu.
author_facet Mayorova, Oksana A.
Grinev, Vyacheslav S.
Yegorova, Alevtina Yu.
author_sort Mayorova, Oksana A.
collection PubMed
description The title compound, C(17)H(10)BrCl(2)NO(2), crystallizes in the monoclinic space group C2/c with a large cell volume of 6207 (3) Å(3). The asymmetric unit of the title compound investigated at 120 K contains two crystallographically independent mol­ecules (Z′ = 2). Each mol­ecule demonstrates slight non-planarity in the solid state and a Z-configuration for the exocyclic C=C bond. The crystal packing reveals the presence of π-π stacking inter­actions between the substituted benzene rings [centroid–centroid distances of 3.836 (5) Å, shift distances in the range 1.272–1.843 Å]. [Image: see text]
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spelling pubmed-94622522022-11-04 (Z)-5-(4-Bromo­phen­yl)-3-{[(3,5-di­chloro­phen­yl)amino]­methyl­idene}furan-2(3H)-one Mayorova, Oksana A. Grinev, Vyacheslav S. Yegorova, Alevtina Yu. IUCrdata Data Reports The title compound, C(17)H(10)BrCl(2)NO(2), crystallizes in the monoclinic space group C2/c with a large cell volume of 6207 (3) Å(3). The asymmetric unit of the title compound investigated at 120 K contains two crystallographically independent mol­ecules (Z′ = 2). Each mol­ecule demonstrates slight non-planarity in the solid state and a Z-configuration for the exocyclic C=C bond. The crystal packing reveals the presence of π-π stacking inter­actions between the substituted benzene rings [centroid–centroid distances of 3.836 (5) Å, shift distances in the range 1.272–1.843 Å]. [Image: see text] International Union of Crystallography 2020-07-17 /pmc/articles/PMC9462252/ /pubmed/36339791 http://dx.doi.org/10.1107/S2414314620009372 Text en © Mayorova et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Mayorova, Oksana A.
Grinev, Vyacheslav S.
Yegorova, Alevtina Yu.
(Z)-5-(4-Bromo­phen­yl)-3-{[(3,5-di­chloro­phen­yl)amino]­methyl­idene}furan-2(3H)-one
title (Z)-5-(4-Bromo­phen­yl)-3-{[(3,5-di­chloro­phen­yl)amino]­methyl­idene}furan-2(3H)-one
title_full (Z)-5-(4-Bromo­phen­yl)-3-{[(3,5-di­chloro­phen­yl)amino]­methyl­idene}furan-2(3H)-one
title_fullStr (Z)-5-(4-Bromo­phen­yl)-3-{[(3,5-di­chloro­phen­yl)amino]­methyl­idene}furan-2(3H)-one
title_full_unstemmed (Z)-5-(4-Bromo­phen­yl)-3-{[(3,5-di­chloro­phen­yl)amino]­methyl­idene}furan-2(3H)-one
title_short (Z)-5-(4-Bromo­phen­yl)-3-{[(3,5-di­chloro­phen­yl)amino]­methyl­idene}furan-2(3H)-one
title_sort (z)-5-(4-bromo­phen­yl)-3-{[(3,5-di­chloro­phen­yl)amino]­methyl­idene}furan-2(3h)-one
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462252/
https://www.ncbi.nlm.nih.gov/pubmed/36339791
http://dx.doi.org/10.1107/S2414314620009372
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