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2-[1-(4-tert-Butyl­phen­yl)-4,5-diphenyl-1H-imid­azol-2-yl]-4,6-di­chloro­phenol

In the title compound, C(31)H(26)Cl(2)N(2)O, the 4,6-di­chloro­phenol and the imidazole rings are almost coplanar, with a dihedral angle of 8.89 (6)° between them and an intra­molecular O—H⋯N hydrogen bond occurs between the rings. The dihedral angles subtended by the tert-butyl­phenyl ring and the...

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Detalles Bibliográficos
Autores principales: Shraddha, K. N., Begum, Noor Shahina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462253/
https://www.ncbi.nlm.nih.gov/pubmed/36339793
http://dx.doi.org/10.1107/S2414314620008706
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author Shraddha, K. N.
Begum, Noor Shahina
author_facet Shraddha, K. N.
Begum, Noor Shahina
author_sort Shraddha, K. N.
collection PubMed
description In the title compound, C(31)H(26)Cl(2)N(2)O, the 4,6-di­chloro­phenol and the imidazole rings are almost coplanar, with a dihedral angle of 8.89 (6)° between them and an intra­molecular O—H⋯N hydrogen bond occurs between the rings. The dihedral angles subtended by the tert-butyl­phenyl ring and the two phenyl rings with the imidazole ring are 85.18 (9), 81.22 (9) and 19.00 (8)°, respectively. The methyl groups of the tert-butyl grouping are disordered over two sets of sites in 0.589 (5):0.411 (5) ratio. In the crystal, inversion dimers linked by pairs of weak C—H⋯Cl inter­actions generate R (2) (2)(24) loops. [Image: see text]
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spelling pubmed-94622532022-11-04 2-[1-(4-tert-Butyl­phen­yl)-4,5-diphenyl-1H-imid­azol-2-yl]-4,6-di­chloro­phenol Shraddha, K. N. Begum, Noor Shahina IUCrdata Data Reports In the title compound, C(31)H(26)Cl(2)N(2)O, the 4,6-di­chloro­phenol and the imidazole rings are almost coplanar, with a dihedral angle of 8.89 (6)° between them and an intra­molecular O—H⋯N hydrogen bond occurs between the rings. The dihedral angles subtended by the tert-butyl­phenyl ring and the two phenyl rings with the imidazole ring are 85.18 (9), 81.22 (9) and 19.00 (8)°, respectively. The methyl groups of the tert-butyl grouping are disordered over two sets of sites in 0.589 (5):0.411 (5) ratio. In the crystal, inversion dimers linked by pairs of weak C—H⋯Cl inter­actions generate R (2) (2)(24) loops. [Image: see text] International Union of Crystallography 2020-07-21 /pmc/articles/PMC9462253/ /pubmed/36339793 http://dx.doi.org/10.1107/S2414314620008706 Text en © Shraddha and Begum 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Shraddha, K. N.
Begum, Noor Shahina
2-[1-(4-tert-Butyl­phen­yl)-4,5-diphenyl-1H-imid­azol-2-yl]-4,6-di­chloro­phenol
title 2-[1-(4-tert-Butyl­phen­yl)-4,5-diphenyl-1H-imid­azol-2-yl]-4,6-di­chloro­phenol
title_full 2-[1-(4-tert-Butyl­phen­yl)-4,5-diphenyl-1H-imid­azol-2-yl]-4,6-di­chloro­phenol
title_fullStr 2-[1-(4-tert-Butyl­phen­yl)-4,5-diphenyl-1H-imid­azol-2-yl]-4,6-di­chloro­phenol
title_full_unstemmed 2-[1-(4-tert-Butyl­phen­yl)-4,5-diphenyl-1H-imid­azol-2-yl]-4,6-di­chloro­phenol
title_short 2-[1-(4-tert-Butyl­phen­yl)-4,5-diphenyl-1H-imid­azol-2-yl]-4,6-di­chloro­phenol
title_sort 2-[1-(4-tert-butyl­phen­yl)-4,5-diphenyl-1h-imid­azol-2-yl]-4,6-di­chloro­phenol
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462253/
https://www.ncbi.nlm.nih.gov/pubmed/36339793
http://dx.doi.org/10.1107/S2414314620008706
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AT begumnoorshahina 214tertbutylphenyl45diphenyl1himidazol2yl46dichlorophenol