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(2-Hy­droxy­phen­yl)(4,2′:4′,4′′-terpyridin-6′-yl)methanone

The title compound, C(22)H(15)N(3)O(2), can be described as a ketone with a phenol substituent and a terpyridine ligand coordinated to the carbonyl group. The three six-membered rings of the terpyridine ligand are not coplanar. The dihedral angles between the mean planes of the central ring and the...

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Detalles Bibliográficos
Autores principales: Devika, S., Begum, Noor Shahina, Manjappa, Kiran B., Yang, Ding-Yah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462256/
https://www.ncbi.nlm.nih.gov/pubmed/36339781
http://dx.doi.org/10.1107/S2414314620008573
Descripción
Sumario:The title compound, C(22)H(15)N(3)O(2), can be described as a ketone with a phenol substituent and a terpyridine ligand coordinated to the carbonyl group. The three six-membered rings of the terpyridine ligand are not coplanar. The dihedral angles between the mean planes of the central ring and the external pyridine ligands are 22.77 (9) and 26.77 (7)°. The central ring of the terpyridine ligand is also not coplanar with the o-hy­droxy phenyl ring, the dihedral angle being 39.72 (5)°. An intra­molecular O—H⋯O hydrogen bond occurs. The crystal structure of the title compound is consolidated by C—H⋯O and C—H⋯N hydrogen bonding inter­actions. [Image: see text]