(2-Hy­droxy­phen­yl)(4,2′:4′,4′′-terpyridin-6′-yl)methanone

The title compound, C(22)H(15)N(3)O(2), can be described as a ketone with a phenol substituent and a terpyridine ligand coordinated to the carbonyl group. The three six-membered rings of the terpyridine ligand are not coplanar. The dihedral angles between the mean planes of the central ring and the...

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Autores principales: Devika, S., Begum, Noor Shahina, Manjappa, Kiran B., Yang, Ding-Yah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462256/
https://www.ncbi.nlm.nih.gov/pubmed/36339781
http://dx.doi.org/10.1107/S2414314620008573
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author Devika, S.
Begum, Noor Shahina
Manjappa, Kiran B.
Yang, Ding-Yah
author_facet Devika, S.
Begum, Noor Shahina
Manjappa, Kiran B.
Yang, Ding-Yah
author_sort Devika, S.
collection PubMed
description The title compound, C(22)H(15)N(3)O(2), can be described as a ketone with a phenol substituent and a terpyridine ligand coordinated to the carbonyl group. The three six-membered rings of the terpyridine ligand are not coplanar. The dihedral angles between the mean planes of the central ring and the external pyridine ligands are 22.77 (9) and 26.77 (7)°. The central ring of the terpyridine ligand is also not coplanar with the o-hy­droxy phenyl ring, the dihedral angle being 39.72 (5)°. An intra­molecular O—H⋯O hydrogen bond occurs. The crystal structure of the title compound is consolidated by C—H⋯O and C—H⋯N hydrogen bonding inter­actions. [Image: see text]
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spelling pubmed-94622562022-11-04 (2-Hy­droxy­phen­yl)(4,2′:4′,4′′-terpyridin-6′-yl)methanone Devika, S. Begum, Noor Shahina Manjappa, Kiran B. Yang, Ding-Yah IUCrdata Data Reports The title compound, C(22)H(15)N(3)O(2), can be described as a ketone with a phenol substituent and a terpyridine ligand coordinated to the carbonyl group. The three six-membered rings of the terpyridine ligand are not coplanar. The dihedral angles between the mean planes of the central ring and the external pyridine ligands are 22.77 (9) and 26.77 (7)°. The central ring of the terpyridine ligand is also not coplanar with the o-hy­droxy phenyl ring, the dihedral angle being 39.72 (5)°. An intra­molecular O—H⋯O hydrogen bond occurs. The crystal structure of the title compound is consolidated by C—H⋯O and C—H⋯N hydrogen bonding inter­actions. [Image: see text] International Union of Crystallography 2020-07-10 /pmc/articles/PMC9462256/ /pubmed/36339781 http://dx.doi.org/10.1107/S2414314620008573 Text en © Devika et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Devika, S.
Begum, Noor Shahina
Manjappa, Kiran B.
Yang, Ding-Yah
(2-Hy­droxy­phen­yl)(4,2′:4′,4′′-terpyridin-6′-yl)methanone
title (2-Hy­droxy­phen­yl)(4,2′:4′,4′′-terpyridin-6′-yl)methanone
title_full (2-Hy­droxy­phen­yl)(4,2′:4′,4′′-terpyridin-6′-yl)methanone
title_fullStr (2-Hy­droxy­phen­yl)(4,2′:4′,4′′-terpyridin-6′-yl)methanone
title_full_unstemmed (2-Hy­droxy­phen­yl)(4,2′:4′,4′′-terpyridin-6′-yl)methanone
title_short (2-Hy­droxy­phen­yl)(4,2′:4′,4′′-terpyridin-6′-yl)methanone
title_sort (2-hy­droxy­phen­yl)(4,2′:4′,4′′-terpyridin-6′-yl)methanone
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462256/
https://www.ncbi.nlm.nih.gov/pubmed/36339781
http://dx.doi.org/10.1107/S2414314620008573
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AT begumnoorshahina 2hydroxyphenyl4244terpyridin6ylmethanone
AT manjappakiranb 2hydroxyphenyl4244terpyridin6ylmethanone
AT yangdingyah 2hydroxyphenyl4244terpyridin6ylmethanone

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