[5,10,15,20-Tetra­kis­(penta­fluoro­phen­yl)porphyrin­ato]zinc(II) benzene disolvate

Single crystals of the title zinc porphyrinato complex, [Zn(C(44)H(8)F(20)N(4))]·2C(6)H(6), were obtained by the solvent evaporation method. The molecular complex exhibits point group symmetry [Image: see text] with the central Zn(II) atom located on an inversion centre. The porphyrinato core is app...

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Detalles Bibliográficos
Autores principales: Lin, Zeyuan, Li, Jianfeng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462257/
https://www.ncbi.nlm.nih.gov/pubmed/36339777
http://dx.doi.org/10.1107/S2414314620008779
Descripción
Sumario:Single crystals of the title zinc porphyrinato complex, [Zn(C(44)H(8)F(20)N(4))]·2C(6)H(6), were obtained by the solvent evaporation method. The molecular complex exhibits point group symmetry [Image: see text] with the central Zn(II) atom located on an inversion centre. The porphyrinato core is approximately planar, and the cation has no other ligating atoms than the four porphyrinato N atoms. π–π inter­actions between benzene solvent mol­ecules and [Zn(TFPP)] units lead to multilayer packing structures. In addition, inter­molecular C—H⋯F hydrogen bonding is observed between [Zn(TFPP)] mol­ecules. [Image: see text]

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