catena-Poly[[(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)]-di-μ-bromido]

In the polymeric title complex, [MnBr(2)(C(10)H(8)N(2))]( n ), the Mn(II) ion, situated on a twofold axis of symmetry, is six-coordinated in a distorted octa­hedral coordination geometry defined by two N atoms from the chelating 2,2′-bi­pyridine ligand and four bridging Br(−) anions. The crystal rev...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462262/
https://www.ncbi.nlm.nih.gov/pubmed/36340471
http://dx.doi.org/10.1107/S2414314621000833
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the polymeric title complex, [MnBr(2)(C(10)H(8)N(2))]( n ), the Mn(II) ion, situated on a twofold axis of symmetry, is six-coordinated in a distorted octa­hedral coordination geometry defined by two N atoms from the chelating 2,2′-bi­pyridine ligand and four bridging Br(−) anions. The crystal reveals a one-dimensional Br-bridged chain along the c-axis direction with a zigzag topology. In the crystals, contacts between chains include π–π inter­actions between pyridyl rings [inter-centroid separation = 4.082 (1) Å] [Image: see text]
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spelling pubmed-94622622022-11-04 catena-Poly[[(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)]-di-μ-bromido] Ha, Kwang IUCrdata Data Reports In the polymeric title complex, [MnBr(2)(C(10)H(8)N(2))]( n ), the Mn(II) ion, situated on a twofold axis of symmetry, is six-coordinated in a distorted octa­hedral coordination geometry defined by two N atoms from the chelating 2,2′-bi­pyridine ligand and four bridging Br(−) anions. The crystal reveals a one-dimensional Br-bridged chain along the c-axis direction with a zigzag topology. In the crystals, contacts between chains include π–π inter­actions between pyridyl rings [inter-centroid separation = 4.082 (1) Å] [Image: see text] International Union of Crystallography 2021-01-29 /pmc/articles/PMC9462262/ /pubmed/36340471 http://dx.doi.org/10.1107/S2414314621000833 Text en © Kwang Ha 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ha, Kwang
catena-Poly[[(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)]-di-μ-bromido]
title catena-Poly[[(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)]-di-μ-bromido]
title_full catena-Poly[[(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)]-di-μ-bromido]
title_fullStr catena-Poly[[(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)]-di-μ-bromido]
title_full_unstemmed catena-Poly[[(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)]-di-μ-bromido]
title_short catena-Poly[[(2,2′-bi­pyridine-κ(2) N,N′)manganese(II)]-di-μ-bromido]
title_sort catena-poly[[(2,2′-bi­pyridine-κ(2) n,n′)manganese(ii)]-di-μ-bromido]
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462262/
https://www.ncbi.nlm.nih.gov/pubmed/36340471
http://dx.doi.org/10.1107/S2414314621000833
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