Di-μ(2)-chlorido-bis­{chlorido­[2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (2),N (1),N (6)]nickel(II)}

In the title compound, [Ni(2)Cl(4)(C(18)H(12)N(6))(2)], the Ni(II) ions are hexa-coordinated in a distorted octa­hedral coordination environment defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and three Cl(−) anions in a meridional geometry. The two Ni(II) ions a...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462264/
https://www.ncbi.nlm.nih.gov/pubmed/36340472
http://dx.doi.org/10.1107/S2414314621000936
Descripción
Sumario:In the title compound, [Ni(2)Cl(4)(C(18)H(12)N(6))(2)], the Ni(II) ions are hexa-coordinated in a distorted octa­hedral coordination environment defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and three Cl(−) anions in a meridional geometry. The two Ni(II) ions are bridged by two Cl anionic ligands, thereby forming a dinuclear complex. A crystallographic centre of inversion is located at the centroid of the Ni(2)Cl(2) ring. [Image: see text]

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