Di-μ(2)-chlorido-bis­{chlorido­[2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (2),N (1),N (6)]nickel(II)}

In the title compound, [Ni(2)Cl(4)(C(18)H(12)N(6))(2)], the Ni(II) ions are hexa-coordinated in a distorted octa­hedral coordination environment defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and three Cl(−) anions in a meridional geometry. The two Ni(II) ions a...

Descripción completa

Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462264/
https://www.ncbi.nlm.nih.gov/pubmed/36340472
http://dx.doi.org/10.1107/S2414314621000936
_version_ 1784787145518481408
author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description In the title compound, [Ni(2)Cl(4)(C(18)H(12)N(6))(2)], the Ni(II) ions are hexa-coordinated in a distorted octa­hedral coordination environment defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and three Cl(−) anions in a meridional geometry. The two Ni(II) ions are bridged by two Cl anionic ligands, thereby forming a dinuclear complex. A crystallographic centre of inversion is located at the centroid of the Ni(2)Cl(2) ring. [Image: see text]
format Online
Article
Text
id pubmed-9462264
institution National Center for Biotechnology Information
language English
publishDate 2021
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-94622642022-11-04 Di-μ(2)-chlorido-bis­{chlorido­[2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (2),N (1),N (6)]nickel(II)} Ha, Kwang IUCrdata Data Reports In the title compound, [Ni(2)Cl(4)(C(18)H(12)N(6))(2)], the Ni(II) ions are hexa-coordinated in a distorted octa­hedral coordination environment defined by three N atoms of the tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine ligand and three Cl(−) anions in a meridional geometry. The two Ni(II) ions are bridged by two Cl anionic ligands, thereby forming a dinuclear complex. A crystallographic centre of inversion is located at the centroid of the Ni(2)Cl(2) ring. [Image: see text] International Union of Crystallography 2021-01-29 /pmc/articles/PMC9462264/ /pubmed/36340472 http://dx.doi.org/10.1107/S2414314621000936 Text en © Kwang Ha 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ha, Kwang
Di-μ(2)-chlorido-bis­{chlorido­[2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (2),N (1),N (6)]nickel(II)}
title Di-μ(2)-chlorido-bis­{chlorido­[2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (2),N (1),N (6)]nickel(II)}
title_full Di-μ(2)-chlorido-bis­{chlorido­[2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (2),N (1),N (6)]nickel(II)}
title_fullStr Di-μ(2)-chlorido-bis­{chlorido­[2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (2),N (1),N (6)]nickel(II)}
title_full_unstemmed Di-μ(2)-chlorido-bis­{chlorido­[2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (2),N (1),N (6)]nickel(II)}
title_short Di-μ(2)-chlorido-bis­{chlorido­[2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) N (2),N (1),N (6)]nickel(II)}
title_sort di-μ(2)-chlorido-bis­{chlorido­[2,4,6-tris­(pyridin-2-yl)-1,3,5-triazine-κ(3) n (2),n (1),n (6)]nickel(ii)}
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462264/
https://www.ncbi.nlm.nih.gov/pubmed/36340472
http://dx.doi.org/10.1107/S2414314621000936
work_keys_str_mv AT hakwang dim2chloridobischlorido246trispyridin2yl135triazinek3n2n1n6nickelii

Ejemplares similares