N-[2-(3,4-Di­meth­oxy­phen­yl)-2-(phenyl­sulfan­yl)eth­yl]-2-(2-fluoro­phen­yl)acetamide

The title compound, C(24)H(24)FNO(3)S, is an inter­mediate in the synthesis of fluorine containing iso­quinoline alkaloids, which crystallizes in the triclinic space group P [Image: see text] with one mol­ecule in the asymmetric unit. The structure presents a racemic mixture of enanti­omers. The C—S...

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Detalles Bibliográficos
Autores principales: Ovalle, Marco A., Romero, José A., Aguirre, Gerardo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462268/
https://www.ncbi.nlm.nih.gov/pubmed/36340467
http://dx.doi.org/10.1107/S2414314620016636
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author Ovalle, Marco A.
Romero, José A.
Aguirre, Gerardo
author_facet Ovalle, Marco A.
Romero, José A.
Aguirre, Gerardo
author_sort Ovalle, Marco A.
collection PubMed
description The title compound, C(24)H(24)FNO(3)S, is an inter­mediate in the synthesis of fluorine containing iso­quinoline alkaloids, which crystallizes in the triclinic space group P [Image: see text] with one mol­ecule in the asymmetric unit. The structure presents a racemic mixture of enanti­omers. The C—S—C—C torsion angle between the benzene ring system and the sulfonyl benzene ring is −178.5 (1)°. In the crystal, N—H⋯O hydrogen bonds between neighbouring mol­ecules form chains of mol­ecules along the a-axis direction. [Image: see text]
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spelling pubmed-94622682022-11-04 N-[2-(3,4-Di­meth­oxy­phen­yl)-2-(phenyl­sulfan­yl)eth­yl]-2-(2-fluoro­phen­yl)acetamide Ovalle, Marco A. Romero, José A. Aguirre, Gerardo IUCrdata Data Reports The title compound, C(24)H(24)FNO(3)S, is an inter­mediate in the synthesis of fluorine containing iso­quinoline alkaloids, which crystallizes in the triclinic space group P [Image: see text] with one mol­ecule in the asymmetric unit. The structure presents a racemic mixture of enanti­omers. The C—S—C—C torsion angle between the benzene ring system and the sulfonyl benzene ring is −178.5 (1)°. In the crystal, N—H⋯O hydrogen bonds between neighbouring mol­ecules form chains of mol­ecules along the a-axis direction. [Image: see text] International Union of Crystallography 2021-01-05 /pmc/articles/PMC9462268/ /pubmed/36340467 http://dx.doi.org/10.1107/S2414314620016636 Text en © Ovalle et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Ovalle, Marco A.
Romero, José A.
Aguirre, Gerardo
N-[2-(3,4-Di­meth­oxy­phen­yl)-2-(phenyl­sulfan­yl)eth­yl]-2-(2-fluoro­phen­yl)acetamide
title N-[2-(3,4-Di­meth­oxy­phen­yl)-2-(phenyl­sulfan­yl)eth­yl]-2-(2-fluoro­phen­yl)acetamide
title_full N-[2-(3,4-Di­meth­oxy­phen­yl)-2-(phenyl­sulfan­yl)eth­yl]-2-(2-fluoro­phen­yl)acetamide
title_fullStr N-[2-(3,4-Di­meth­oxy­phen­yl)-2-(phenyl­sulfan­yl)eth­yl]-2-(2-fluoro­phen­yl)acetamide
title_full_unstemmed N-[2-(3,4-Di­meth­oxy­phen­yl)-2-(phenyl­sulfan­yl)eth­yl]-2-(2-fluoro­phen­yl)acetamide
title_short N-[2-(3,4-Di­meth­oxy­phen­yl)-2-(phenyl­sulfan­yl)eth­yl]-2-(2-fluoro­phen­yl)acetamide
title_sort n-[2-(3,4-di­meth­oxy­phen­yl)-2-(phenyl­sulfan­yl)eth­yl]-2-(2-fluoro­phen­yl)acetamide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462268/
https://www.ncbi.nlm.nih.gov/pubmed/36340467
http://dx.doi.org/10.1107/S2414314620016636
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