{4,4′-Di­bromo-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato-κ(4) O,N,N′,O′}nickel(II)

In the title compound, [Ni(C(20)H(18)Br(2)N(2)O(2))], the Ni(II) ion is four-coordinated in a slightly distorted square-planar coordination geometry defined by two N atoms and two O atoms of the tetra­dentate dianionic 4,4′-di­bromo-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolat...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462270/
https://www.ncbi.nlm.nih.gov/pubmed/36340466
http://dx.doi.org/10.1107/S2414314621000845
Descripción
Sumario:In the title compound, [Ni(C(20)H(18)Br(2)N(2)O(2))], the Ni(II) ion is four-coordinated in a slightly distorted square-planar coordination geometry defined by two N atoms and two O atoms of the tetra­dentate dianionic 4,4′-di­bromo-2,2′-[cyclo­hexane-1,2-diylbis(nitrilo­methanylyl­idene)]diphenolato ligand. Pairs of complex mol­ecules are assembled by inter­molecular C—H⋯O hydrogen bonds with d(C⋯O) = 3.247 (4) Å. [Image: see text]

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