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{4,4′-Dibromo-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II)
In the title compound, [Ni(C(20)H(18)Br(2)N(2)O(2))], the Ni(II) ion is four-coordinated in a slightly distorted square-planar coordination geometry defined by two N atoms and two O atoms of the tetradentate dianionic 4,4′-dibromo-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolat...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462270/ https://www.ncbi.nlm.nih.gov/pubmed/36340466 http://dx.doi.org/10.1107/S2414314621000845 |
| _version_ | 1784787146979147776 |
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| author | Ha, Kwang |
| author_facet | Ha, Kwang |
| author_sort | Ha, Kwang |
| collection | PubMed |
| description | In the title compound, [Ni(C(20)H(18)Br(2)N(2)O(2))], the Ni(II) ion is four-coordinated in a slightly distorted square-planar coordination geometry defined by two N atoms and two O atoms of the tetradentate dianionic 4,4′-dibromo-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato ligand. Pairs of complex molecules are assembled by intermolecular C—H⋯O hydrogen bonds with d(C⋯O) = 3.247 (4) Å. [Image: see text] |
| format | Online Article Text |
| id | pubmed-9462270 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2021 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-94622702022-11-04 {4,4′-Dibromo-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II) Ha, Kwang IUCrdata Data Reports In the title compound, [Ni(C(20)H(18)Br(2)N(2)O(2))], the Ni(II) ion is four-coordinated in a slightly distorted square-planar coordination geometry defined by two N atoms and two O atoms of the tetradentate dianionic 4,4′-dibromo-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato ligand. Pairs of complex molecules are assembled by intermolecular C—H⋯O hydrogen bonds with d(C⋯O) = 3.247 (4) Å. [Image: see text] International Union of Crystallography 2021-01-29 /pmc/articles/PMC9462270/ /pubmed/36340466 http://dx.doi.org/10.1107/S2414314621000845 Text en © Kwang Ha 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Data Reports Ha, Kwang {4,4′-Dibromo-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(4) O,N,N′,O′}nickel(II) |
| title | {4,4′-Dibromo-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_full | {4,4′-Dibromo-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_fullStr | {4,4′-Dibromo-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_full_unstemmed | {4,4′-Dibromo-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_short | {4,4′-Dibromo-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
O,N,N′,O′}nickel(II) |
| title_sort | {4,4′-dibromo-2,2′-[cyclohexane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-κ(4)
o,n,n′,o′}nickel(ii) |
| topic | Data Reports |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462270/ https://www.ncbi.nlm.nih.gov/pubmed/36340466 http://dx.doi.org/10.1107/S2414314621000845 |
| work_keys_str_mv | AT hakwang 44dibromo22cyclohexane12diylbisnitrilomethanylylidenediphenolatok4onnonickelii |