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trans-Di­aqua­bis­(N,N,N′-tri­methyl­ethylenedi­amine)­nickel(II) dichloride

In the title salt, [Ni(C(5)H(12)N(2))(2)(H(2)O)(2)]Cl(2), the asymmetric unit is comprised of half of the complex cation and a chloride ion with the Ni(II) atom of the cation situated about a twofold rotation axis. The six-coordinate Ni(II) atom of the cation is connected to four N atoms from two me...

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Detalles Bibliográficos
Autores principales: Miecznikowski, John R., Jasinski, Jerry P., Flaherty, Nicole F., Mircovich, Emma E., Smolinsky, Allison N., Bertolotti, Natalia R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462272/
https://www.ncbi.nlm.nih.gov/pubmed/36338915
http://dx.doi.org/10.1107/S2414314620011827
Descripción
Sumario:In the title salt, [Ni(C(5)H(12)N(2))(2)(H(2)O)(2)]Cl(2), the asymmetric unit is comprised of half of the complex cation and a chloride ion with the Ni(II) atom of the cation situated about a twofold rotation axis. The six-coordinate Ni(II) atom of the cation is connected to four N atoms from two methyl-substituted ethyelenedi­amine ligands and two water mol­ecules in a slightly distorted octa­hedral environment. The five-membered chelate ring is in a slight envelope conformation. The crystal packing features O—H⋯Cl and N—H⋯Cl inter­molecular inter­actions with the Cl(−) ion forming weak bifurcated hydrogen bonds with nearby water mol­ecules and N—H inter­actions, leading to a three-dimensional supra­molecular network structure. [Image: see text]