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trans-Di­aqua­bis­(N,N,N′-tri­methyl­ethylenedi­amine)­nickel(II) dichloride

In the title salt, [Ni(C(5)H(12)N(2))(2)(H(2)O)(2)]Cl(2), the asymmetric unit is comprised of half of the complex cation and a chloride ion with the Ni(II) atom of the cation situated about a twofold rotation axis. The six-coordinate Ni(II) atom of the cation is connected to four N atoms from two me...

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Autores principales: Miecznikowski, John R., Jasinski, Jerry P., Flaherty, Nicole F., Mircovich, Emma E., Smolinsky, Allison N., Bertolotti, Natalia R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462272/
https://www.ncbi.nlm.nih.gov/pubmed/36338915
http://dx.doi.org/10.1107/S2414314620011827
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author Miecznikowski, John R.
Jasinski, Jerry P.
Flaherty, Nicole F.
Mircovich, Emma E.
Smolinsky, Allison N.
Bertolotti, Natalia R.
author_facet Miecznikowski, John R.
Jasinski, Jerry P.
Flaherty, Nicole F.
Mircovich, Emma E.
Smolinsky, Allison N.
Bertolotti, Natalia R.
author_sort Miecznikowski, John R.
collection PubMed
description In the title salt, [Ni(C(5)H(12)N(2))(2)(H(2)O)(2)]Cl(2), the asymmetric unit is comprised of half of the complex cation and a chloride ion with the Ni(II) atom of the cation situated about a twofold rotation axis. The six-coordinate Ni(II) atom of the cation is connected to four N atoms from two methyl-substituted ethyelenedi­amine ligands and two water mol­ecules in a slightly distorted octa­hedral environment. The five-membered chelate ring is in a slight envelope conformation. The crystal packing features O—H⋯Cl and N—H⋯Cl inter­molecular inter­actions with the Cl(−) ion forming weak bifurcated hydrogen bonds with nearby water mol­ecules and N—H inter­actions, leading to a three-dimensional supra­molecular network structure. [Image: see text]
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spelling pubmed-94622722022-11-04 trans-Di­aqua­bis­(N,N,N′-tri­methyl­ethylenedi­amine)­nickel(II) dichloride Miecznikowski, John R. Jasinski, Jerry P. Flaherty, Nicole F. Mircovich, Emma E. Smolinsky, Allison N. Bertolotti, Natalia R. IUCrdata Data Reports In the title salt, [Ni(C(5)H(12)N(2))(2)(H(2)O)(2)]Cl(2), the asymmetric unit is comprised of half of the complex cation and a chloride ion with the Ni(II) atom of the cation situated about a twofold rotation axis. The six-coordinate Ni(II) atom of the cation is connected to four N atoms from two methyl-substituted ethyelenedi­amine ligands and two water mol­ecules in a slightly distorted octa­hedral environment. The five-membered chelate ring is in a slight envelope conformation. The crystal packing features O—H⋯Cl and N—H⋯Cl inter­molecular inter­actions with the Cl(−) ion forming weak bifurcated hydrogen bonds with nearby water mol­ecules and N—H inter­actions, leading to a three-dimensional supra­molecular network structure. [Image: see text] International Union of Crystallography 2020-09-08 /pmc/articles/PMC9462272/ /pubmed/36338915 http://dx.doi.org/10.1107/S2414314620011827 Text en © Miecznikowski et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Miecznikowski, John R.
Jasinski, Jerry P.
Flaherty, Nicole F.
Mircovich, Emma E.
Smolinsky, Allison N.
Bertolotti, Natalia R.
trans-Di­aqua­bis­(N,N,N′-tri­methyl­ethylenedi­amine)­nickel(II) dichloride
title trans-Di­aqua­bis­(N,N,N′-tri­methyl­ethylenedi­amine)­nickel(II) dichloride
title_full trans-Di­aqua­bis­(N,N,N′-tri­methyl­ethylenedi­amine)­nickel(II) dichloride
title_fullStr trans-Di­aqua­bis­(N,N,N′-tri­methyl­ethylenedi­amine)­nickel(II) dichloride
title_full_unstemmed trans-Di­aqua­bis­(N,N,N′-tri­methyl­ethylenedi­amine)­nickel(II) dichloride
title_short trans-Di­aqua­bis­(N,N,N′-tri­methyl­ethylenedi­amine)­nickel(II) dichloride
title_sort trans-di­aqua­bis­(n,n,n′-tri­methyl­ethylenedi­amine)­nickel(ii) dichloride
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462272/
https://www.ncbi.nlm.nih.gov/pubmed/36338915
http://dx.doi.org/10.1107/S2414314620011827
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