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trans-Diaquabis(N,N,N′-trimethylethylenediamine)nickel(II) dichloride
In the title salt, [Ni(C(5)H(12)N(2))(2)(H(2)O)(2)]Cl(2), the asymmetric unit is comprised of half of the complex cation and a chloride ion with the Ni(II) atom of the cation situated about a twofold rotation axis. The six-coordinate Ni(II) atom of the cation is connected to four N atoms from two me...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462272/ https://www.ncbi.nlm.nih.gov/pubmed/36338915 http://dx.doi.org/10.1107/S2414314620011827 |
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author | Miecznikowski, John R. Jasinski, Jerry P. Flaherty, Nicole F. Mircovich, Emma E. Smolinsky, Allison N. Bertolotti, Natalia R. |
author_facet | Miecznikowski, John R. Jasinski, Jerry P. Flaherty, Nicole F. Mircovich, Emma E. Smolinsky, Allison N. Bertolotti, Natalia R. |
author_sort | Miecznikowski, John R. |
collection | PubMed |
description | In the title salt, [Ni(C(5)H(12)N(2))(2)(H(2)O)(2)]Cl(2), the asymmetric unit is comprised of half of the complex cation and a chloride ion with the Ni(II) atom of the cation situated about a twofold rotation axis. The six-coordinate Ni(II) atom of the cation is connected to four N atoms from two methyl-substituted ethyelenediamine ligands and two water molecules in a slightly distorted octahedral environment. The five-membered chelate ring is in a slight envelope conformation. The crystal packing features O—H⋯Cl and N—H⋯Cl intermolecular interactions with the Cl(−) ion forming weak bifurcated hydrogen bonds with nearby water molecules and N—H interactions, leading to a three-dimensional supramolecular network structure. [Image: see text] |
format | Online Article Text |
id | pubmed-9462272 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-94622722022-11-04 trans-Diaquabis(N,N,N′-trimethylethylenediamine)nickel(II) dichloride Miecznikowski, John R. Jasinski, Jerry P. Flaherty, Nicole F. Mircovich, Emma E. Smolinsky, Allison N. Bertolotti, Natalia R. IUCrdata Data Reports In the title salt, [Ni(C(5)H(12)N(2))(2)(H(2)O)(2)]Cl(2), the asymmetric unit is comprised of half of the complex cation and a chloride ion with the Ni(II) atom of the cation situated about a twofold rotation axis. The six-coordinate Ni(II) atom of the cation is connected to four N atoms from two methyl-substituted ethyelenediamine ligands and two water molecules in a slightly distorted octahedral environment. The five-membered chelate ring is in a slight envelope conformation. The crystal packing features O—H⋯Cl and N—H⋯Cl intermolecular interactions with the Cl(−) ion forming weak bifurcated hydrogen bonds with nearby water molecules and N—H interactions, leading to a three-dimensional supramolecular network structure. [Image: see text] International Union of Crystallography 2020-09-08 /pmc/articles/PMC9462272/ /pubmed/36338915 http://dx.doi.org/10.1107/S2414314620011827 Text en © Miecznikowski et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Miecznikowski, John R. Jasinski, Jerry P. Flaherty, Nicole F. Mircovich, Emma E. Smolinsky, Allison N. Bertolotti, Natalia R. trans-Diaquabis(N,N,N′-trimethylethylenediamine)nickel(II) dichloride |
title |
trans-Diaquabis(N,N,N′-trimethylethylenediamine)nickel(II) dichloride |
title_full |
trans-Diaquabis(N,N,N′-trimethylethylenediamine)nickel(II) dichloride |
title_fullStr |
trans-Diaquabis(N,N,N′-trimethylethylenediamine)nickel(II) dichloride |
title_full_unstemmed |
trans-Diaquabis(N,N,N′-trimethylethylenediamine)nickel(II) dichloride |
title_short |
trans-Diaquabis(N,N,N′-trimethylethylenediamine)nickel(II) dichloride |
title_sort | trans-diaquabis(n,n,n′-trimethylethylenediamine)nickel(ii) dichloride |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462272/ https://www.ncbi.nlm.nih.gov/pubmed/36338915 http://dx.doi.org/10.1107/S2414314620011827 |
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