2,2-Bis[3,5-bis­(di­methyl­amino)­phen­yl]-1,1,1,3,3,3-hexa­methyl­tris­ilane

The title compound, C(26)H(48)N(4)Si(3), was synthesized by the reaction of 2,2-di­chloro­tris­ilane with 3,5-bis­(di­methyl­amino)­phenyl­lithium. In the mol­ecule, the dihedral angle between the benzene rings is 57.57 (7)° and the Si—Si—Si bond angle is 110.08 (2)°. In the crystal, mol­ecules are...

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Detalles Bibliográficos
Autores principales: Mizuhata, Yoshiyuki, Iwai, Kento, Tokitoh, Norihiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462273/
https://www.ncbi.nlm.nih.gov/pubmed/36338903
http://dx.doi.org/10.1107/S2414314620012997
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author Mizuhata, Yoshiyuki
Iwai, Kento
Tokitoh, Norihiro
author_facet Mizuhata, Yoshiyuki
Iwai, Kento
Tokitoh, Norihiro
author_sort Mizuhata, Yoshiyuki
collection PubMed
description The title compound, C(26)H(48)N(4)Si(3), was synthesized by the reaction of 2,2-di­chloro­tris­ilane with 3,5-bis­(di­methyl­amino)­phenyl­lithium. In the mol­ecule, the dihedral angle between the benzene rings is 57.57 (7)° and the Si—Si—Si bond angle is 110.08 (2)°. In the crystal, mol­ecules are linked via an SiC–H⋯π(ar­yl) inter­action, forming a chain along the c-axis direction. [Image: see text]
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spelling pubmed-94622732022-11-04 2,2-Bis[3,5-bis­(di­methyl­amino)­phen­yl]-1,1,1,3,3,3-hexa­methyl­tris­ilane Mizuhata, Yoshiyuki Iwai, Kento Tokitoh, Norihiro IUCrdata Data Reports The title compound, C(26)H(48)N(4)Si(3), was synthesized by the reaction of 2,2-di­chloro­tris­ilane with 3,5-bis­(di­methyl­amino)­phenyl­lithium. In the mol­ecule, the dihedral angle between the benzene rings is 57.57 (7)° and the Si—Si—Si bond angle is 110.08 (2)°. In the crystal, mol­ecules are linked via an SiC–H⋯π(ar­yl) inter­action, forming a chain along the c-axis direction. [Image: see text] International Union of Crystallography 2020-09-25 /pmc/articles/PMC9462273/ /pubmed/36338903 http://dx.doi.org/10.1107/S2414314620012997 Text en © Mizuhata et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Mizuhata, Yoshiyuki
Iwai, Kento
Tokitoh, Norihiro
2,2-Bis[3,5-bis­(di­methyl­amino)­phen­yl]-1,1,1,3,3,3-hexa­methyl­tris­ilane
title 2,2-Bis[3,5-bis­(di­methyl­amino)­phen­yl]-1,1,1,3,3,3-hexa­methyl­tris­ilane
title_full 2,2-Bis[3,5-bis­(di­methyl­amino)­phen­yl]-1,1,1,3,3,3-hexa­methyl­tris­ilane
title_fullStr 2,2-Bis[3,5-bis­(di­methyl­amino)­phen­yl]-1,1,1,3,3,3-hexa­methyl­tris­ilane
title_full_unstemmed 2,2-Bis[3,5-bis­(di­methyl­amino)­phen­yl]-1,1,1,3,3,3-hexa­methyl­tris­ilane
title_short 2,2-Bis[3,5-bis­(di­methyl­amino)­phen­yl]-1,1,1,3,3,3-hexa­methyl­tris­ilane
title_sort 2,2-bis[3,5-bis­(di­methyl­amino)­phen­yl]-1,1,1,3,3,3-hexa­methyl­tris­ilane
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462273/
https://www.ncbi.nlm.nih.gov/pubmed/36338903
http://dx.doi.org/10.1107/S2414314620012997
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AT iwaikento 22bis35bisdimethylaminophenyl111333hexamethyltrisilane
AT tokitohnorihiro 22bis35bisdimethylaminophenyl111333hexamethyltrisilane

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