6-(3,4-Di­fluoro­phen­yl)-7,8,13,14-tetra­hydro­dibenzo[c,k]phenanthridine

In the title compound, C(27)H(19)F(2)N, the five-fused-ring system is highly puckered and the dihedral angle between the central pyridine ring and pendant di­fluoro­benzene ring is 45.12 (12)°. In the crystal, inversion dimers linked by pairwise weak C—H⋯N hydrogen bonds generate R (2) (2)(12) loops...

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Detalles Bibliográficos
Autores principales: Fang, Yiwen, Liu, Bingbing, Jia, Zhixiang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462275/
https://www.ncbi.nlm.nih.gov/pubmed/36338910
http://dx.doi.org/10.1107/S2414314620012419
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author Fang, Yiwen
Liu, Bingbing
Jia, Zhixiang
author_facet Fang, Yiwen
Liu, Bingbing
Jia, Zhixiang
author_sort Fang, Yiwen
collection PubMed
description In the title compound, C(27)H(19)F(2)N, the five-fused-ring system is highly puckered and the dihedral angle between the central pyridine ring and pendant di­fluoro­benzene ring is 45.12 (12)°. In the crystal, inversion dimers linked by pairwise weak C—H⋯N hydrogen bonds generate R (2) (2)(12) loops and the dimers are further linked by weak C—H⋯F inter­actions to form [ [Image: see text] 01] chains. [Image: see text]
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spelling pubmed-94622752022-11-04 6-(3,4-Di­fluoro­phen­yl)-7,8,13,14-tetra­hydro­dibenzo[c,k]phenanthridine Fang, Yiwen Liu, Bingbing Jia, Zhixiang IUCrdata Data Reports In the title compound, C(27)H(19)F(2)N, the five-fused-ring system is highly puckered and the dihedral angle between the central pyridine ring and pendant di­fluoro­benzene ring is 45.12 (12)°. In the crystal, inversion dimers linked by pairwise weak C—H⋯N hydrogen bonds generate R (2) (2)(12) loops and the dimers are further linked by weak C—H⋯F inter­actions to form [ [Image: see text] 01] chains. [Image: see text] International Union of Crystallography 2020-09-11 /pmc/articles/PMC9462275/ /pubmed/36338910 http://dx.doi.org/10.1107/S2414314620012419 Text en © Fang et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Fang, Yiwen
Liu, Bingbing
Jia, Zhixiang
6-(3,4-Di­fluoro­phen­yl)-7,8,13,14-tetra­hydro­dibenzo[c,k]phenanthridine
title 6-(3,4-Di­fluoro­phen­yl)-7,8,13,14-tetra­hydro­dibenzo[c,k]phenanthridine
title_full 6-(3,4-Di­fluoro­phen­yl)-7,8,13,14-tetra­hydro­dibenzo[c,k]phenanthridine
title_fullStr 6-(3,4-Di­fluoro­phen­yl)-7,8,13,14-tetra­hydro­dibenzo[c,k]phenanthridine
title_full_unstemmed 6-(3,4-Di­fluoro­phen­yl)-7,8,13,14-tetra­hydro­dibenzo[c,k]phenanthridine
title_short 6-(3,4-Di­fluoro­phen­yl)-7,8,13,14-tetra­hydro­dibenzo[c,k]phenanthridine
title_sort 6-(3,4-di­fluoro­phen­yl)-7,8,13,14-tetra­hydro­dibenzo[c,k]phenanthridine
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462275/
https://www.ncbi.nlm.nih.gov/pubmed/36338910
http://dx.doi.org/10.1107/S2414314620012419
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AT jiazhixiang 634difluorophenyl781314tetrahydrodibenzockphenanthridine

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