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rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabi­cyclo­[6.3.0]undec-4-ene

In the title compound, a cyclo­octene ring in a twist-boat conformation and a dioxolane ring with a distorted envelope conformation are annulated in a trans configuration. Alternating strands of single enanti­omers build up the crystal. Within the strands, the mol­ecules are connected by weak C—H⋯O...

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Detalles Bibliográficos
Autores principales: Schollmeyer, Dieter, Heidrich, Maximilian, Detert, Heiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462276/
https://www.ncbi.nlm.nih.gov/pubmed/36338907
http://dx.doi.org/10.1107/S2414314620013024
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author Schollmeyer, Dieter
Heidrich, Maximilian
Detert, Heiner
author_facet Schollmeyer, Dieter
Heidrich, Maximilian
Detert, Heiner
author_sort Schollmeyer, Dieter
collection PubMed
description In the title compound, a cyclo­octene ring in a twist-boat conformation and a dioxolane ring with a distorted envelope conformation are annulated in a trans configuration. Alternating strands of single enanti­omers build up the crystal. Within the strands, the mol­ecules are connected by weak C—H⋯O hydrogen bonds. [Image: see text]
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spelling pubmed-94622762022-11-04 rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabi­cyclo­[6.3.0]undec-4-ene Schollmeyer, Dieter Heidrich, Maximilian Detert, Heiner IUCrdata Data Reports In the title compound, a cyclo­octene ring in a twist-boat conformation and a dioxolane ring with a distorted envelope conformation are annulated in a trans configuration. Alternating strands of single enanti­omers build up the crystal. Within the strands, the mol­ecules are connected by weak C—H⋯O hydrogen bonds. [Image: see text] International Union of Crystallography 2020-09-30 /pmc/articles/PMC9462276/ /pubmed/36338907 http://dx.doi.org/10.1107/S2414314620013024 Text en © Schollmeyer et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Schollmeyer, Dieter
Heidrich, Maximilian
Detert, Heiner
rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabi­cyclo­[6.3.0]undec-4-ene
title rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabi­cyclo­[6.3.0]undec-4-ene
title_full rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabi­cyclo­[6.3.0]undec-4-ene
title_fullStr rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabi­cyclo­[6.3.0]undec-4-ene
title_full_unstemmed rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabi­cyclo­[6.3.0]undec-4-ene
title_short rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabi­cyclo­[6.3.0]undec-4-ene
title_sort rac-(e,trans)-4-bromo-10,10-dimethyl-9,11-dioxabi­cyclo­[6.3.0]undec-4-ene
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462276/
https://www.ncbi.nlm.nih.gov/pubmed/36338907
http://dx.doi.org/10.1107/S2414314620013024
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