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rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabicyclo[6.3.0]undec-4-ene
In the title compound, a cyclooctene ring in a twist-boat conformation and a dioxolane ring with a distorted envelope conformation are annulated in a trans configuration. Alternating strands of single enantiomers build up the crystal. Within the strands, the molecules are connected by weak C—H⋯O...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462276/ https://www.ncbi.nlm.nih.gov/pubmed/36338907 http://dx.doi.org/10.1107/S2414314620013024 |
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author | Schollmeyer, Dieter Heidrich, Maximilian Detert, Heiner |
author_facet | Schollmeyer, Dieter Heidrich, Maximilian Detert, Heiner |
author_sort | Schollmeyer, Dieter |
collection | PubMed |
description | In the title compound, a cyclooctene ring in a twist-boat conformation and a dioxolane ring with a distorted envelope conformation are annulated in a trans configuration. Alternating strands of single enantiomers build up the crystal. Within the strands, the molecules are connected by weak C—H⋯O hydrogen bonds. [Image: see text] |
format | Online Article Text |
id | pubmed-9462276 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-94622762022-11-04 rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabicyclo[6.3.0]undec-4-ene Schollmeyer, Dieter Heidrich, Maximilian Detert, Heiner IUCrdata Data Reports In the title compound, a cyclooctene ring in a twist-boat conformation and a dioxolane ring with a distorted envelope conformation are annulated in a trans configuration. Alternating strands of single enantiomers build up the crystal. Within the strands, the molecules are connected by weak C—H⋯O hydrogen bonds. [Image: see text] International Union of Crystallography 2020-09-30 /pmc/articles/PMC9462276/ /pubmed/36338907 http://dx.doi.org/10.1107/S2414314620013024 Text en © Schollmeyer et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Schollmeyer, Dieter Heidrich, Maximilian Detert, Heiner rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabicyclo[6.3.0]undec-4-ene |
title |
rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabicyclo[6.3.0]undec-4-ene |
title_full |
rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabicyclo[6.3.0]undec-4-ene |
title_fullStr |
rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabicyclo[6.3.0]undec-4-ene |
title_full_unstemmed |
rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabicyclo[6.3.0]undec-4-ene |
title_short |
rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabicyclo[6.3.0]undec-4-ene |
title_sort | rac-(e,trans)-4-bromo-10,10-dimethyl-9,11-dioxabicyclo[6.3.0]undec-4-ene |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462276/ https://www.ncbi.nlm.nih.gov/pubmed/36338907 http://dx.doi.org/10.1107/S2414314620013024 |
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