Di­aqua­bis­(4-ferrocenyl-1,1,1-tri­fluoro-4-oxobutan-2-olato)cobalt(II)

In the title compound, [CoFe(2)(C(5)H(5))(2)(C(9)H(5)F(3)O(2))(2)(H(2)O)(2)], the central Co atom has an octa­hedral coordination geometry defined by two chelating tri­fluoro­methyl-β-diketone ferrocene ligands and two aqua ligands, with the latter in a cis disposition. The Cp rings in both ferrocen...

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Detalles Bibliográficos
Autores principales: Wang, Shujing, Han, Heguo, Han, Yuyang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462279/
https://www.ncbi.nlm.nih.gov/pubmed/36338901
http://dx.doi.org/10.1107/S2414314620012407
Descripción
Sumario:In the title compound, [CoFe(2)(C(5)H(5))(2)(C(9)H(5)F(3)O(2))(2)(H(2)O)(2)], the central Co atom has an octa­hedral coordination geometry defined by two chelating tri­fluoro­methyl-β-diketone ferrocene ligands and two aqua ligands, with the latter in a cis disposition. The Cp rings in both ferrocene groupings are close to eclipsed. In the crystal, O—H⋯O hydrogen bonds link the mol­ecules into [100] chains. [Image: see text]

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