Di­aqua­bis­(4-ferrocenyl-1,1,1-tri­fluoro-4-oxobutan-2-olato)cobalt(II)

In the title compound, [CoFe(2)(C(5)H(5))(2)(C(9)H(5)F(3)O(2))(2)(H(2)O)(2)], the central Co atom has an octa­hedral coordination geometry defined by two chelating tri­fluoro­methyl-β-diketone ferrocene ligands and two aqua ligands, with the latter in a cis disposition. The Cp rings in both ferrocen...

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Detalles Bibliográficos
Autores principales: Wang, Shujing, Han, Heguo, Han, Yuyang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462279/
https://www.ncbi.nlm.nih.gov/pubmed/36338901
http://dx.doi.org/10.1107/S2414314620012407
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author Wang, Shujing
Han, Heguo
Han, Yuyang
author_facet Wang, Shujing
Han, Heguo
Han, Yuyang
author_sort Wang, Shujing
collection PubMed
description In the title compound, [CoFe(2)(C(5)H(5))(2)(C(9)H(5)F(3)O(2))(2)(H(2)O)(2)], the central Co atom has an octa­hedral coordination geometry defined by two chelating tri­fluoro­methyl-β-diketone ferrocene ligands and two aqua ligands, with the latter in a cis disposition. The Cp rings in both ferrocene groupings are close to eclipsed. In the crystal, O—H⋯O hydrogen bonds link the mol­ecules into [100] chains. [Image: see text]
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spelling pubmed-94622792022-11-04 Di­aqua­bis­(4-ferrocenyl-1,1,1-tri­fluoro-4-oxobutan-2-olato)cobalt(II) Wang, Shujing Han, Heguo Han, Yuyang IUCrdata Data Reports In the title compound, [CoFe(2)(C(5)H(5))(2)(C(9)H(5)F(3)O(2))(2)(H(2)O)(2)], the central Co atom has an octa­hedral coordination geometry defined by two chelating tri­fluoro­methyl-β-diketone ferrocene ligands and two aqua ligands, with the latter in a cis disposition. The Cp rings in both ferrocene groupings are close to eclipsed. In the crystal, O—H⋯O hydrogen bonds link the mol­ecules into [100] chains. [Image: see text] International Union of Crystallography 2020-09-11 /pmc/articles/PMC9462279/ /pubmed/36338901 http://dx.doi.org/10.1107/S2414314620012407 Text en © Wang et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Wang, Shujing
Han, Heguo
Han, Yuyang
Di­aqua­bis­(4-ferrocenyl-1,1,1-tri­fluoro-4-oxobutan-2-olato)cobalt(II)
title Di­aqua­bis­(4-ferrocenyl-1,1,1-tri­fluoro-4-oxobutan-2-olato)cobalt(II)
title_full Di­aqua­bis­(4-ferrocenyl-1,1,1-tri­fluoro-4-oxobutan-2-olato)cobalt(II)
title_fullStr Di­aqua­bis­(4-ferrocenyl-1,1,1-tri­fluoro-4-oxobutan-2-olato)cobalt(II)
title_full_unstemmed Di­aqua­bis­(4-ferrocenyl-1,1,1-tri­fluoro-4-oxobutan-2-olato)cobalt(II)
title_short Di­aqua­bis­(4-ferrocenyl-1,1,1-tri­fluoro-4-oxobutan-2-olato)cobalt(II)
title_sort di­aqua­bis­(4-ferrocenyl-1,1,1-tri­fluoro-4-oxobutan-2-olato)cobalt(ii)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462279/
https://www.ncbi.nlm.nih.gov/pubmed/36338901
http://dx.doi.org/10.1107/S2414314620012407
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