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Bis[tris(pyridin-2-yl)amine]iron(II) tris(dicyanomethylidene)methanediide
In the title compound, [Fe{(C(5)H(4)N)(3)N}(2)][C{C(CN)(2)}(3)], both ions lie across centres of inversion, with the anion being statistically disordered over two sets of atomic sites having equal occupancy. The cation and anion have approximate [Image: see text] and 32 symmetry, respectively, and t...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462281/ https://www.ncbi.nlm.nih.gov/pubmed/36338914 http://dx.doi.org/10.1107/S241431462001278X |
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author | Setifi, Zouaoui Setifi, Fatima Dege, Necmi Al-Douh, Mohammed Hadi Glidewell, Christopher |
author_facet | Setifi, Zouaoui Setifi, Fatima Dege, Necmi Al-Douh, Mohammed Hadi Glidewell, Christopher |
author_sort | Setifi, Zouaoui |
collection | PubMed |
description | In the title compound, [Fe{(C(5)H(4)N)(3)N}(2)][C{C(CN)(2)}(3)], both ions lie across centres of inversion, with the anion being statistically disordered over two sets of atomic sites having equal occupancy. The cation and anion have approximate [Image: see text] and 32 symmetry, respectively, and the Fe—N bond lengths indicate low-spin Fe(II). A combination of two-centre C—H⋯N and three-centre C—H⋯(N)(2) hydrogen bonds link the ions into complex sheets. Several low-occupancy water molecules are present, whose H atoms could not be located: accordingly, the reflection data were subjected to the SQUEEZE procedure [Spek (2015 ▸). Acta Cryst. C71, 9–18]. [Image: see text] |
format | Online Article Text |
id | pubmed-9462281 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2020 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-94622812022-11-04 Bis[tris(pyridin-2-yl)amine]iron(II) tris(dicyanomethylidene)methanediide Setifi, Zouaoui Setifi, Fatima Dege, Necmi Al-Douh, Mohammed Hadi Glidewell, Christopher IUCrdata Data Reports In the title compound, [Fe{(C(5)H(4)N)(3)N}(2)][C{C(CN)(2)}(3)], both ions lie across centres of inversion, with the anion being statistically disordered over two sets of atomic sites having equal occupancy. The cation and anion have approximate [Image: see text] and 32 symmetry, respectively, and the Fe—N bond lengths indicate low-spin Fe(II). A combination of two-centre C—H⋯N and three-centre C—H⋯(N)(2) hydrogen bonds link the ions into complex sheets. Several low-occupancy water molecules are present, whose H atoms could not be located: accordingly, the reflection data were subjected to the SQUEEZE procedure [Spek (2015 ▸). Acta Cryst. C71, 9–18]. [Image: see text] International Union of Crystallography 2020-09-25 /pmc/articles/PMC9462281/ /pubmed/36338914 http://dx.doi.org/10.1107/S241431462001278X Text en © Setifi et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Setifi, Zouaoui Setifi, Fatima Dege, Necmi Al-Douh, Mohammed Hadi Glidewell, Christopher Bis[tris(pyridin-2-yl)amine]iron(II) tris(dicyanomethylidene)methanediide |
title | Bis[tris(pyridin-2-yl)amine]iron(II) tris(dicyanomethylidene)methanediide |
title_full | Bis[tris(pyridin-2-yl)amine]iron(II) tris(dicyanomethylidene)methanediide |
title_fullStr | Bis[tris(pyridin-2-yl)amine]iron(II) tris(dicyanomethylidene)methanediide |
title_full_unstemmed | Bis[tris(pyridin-2-yl)amine]iron(II) tris(dicyanomethylidene)methanediide |
title_short | Bis[tris(pyridin-2-yl)amine]iron(II) tris(dicyanomethylidene)methanediide |
title_sort | bis[tris(pyridin-2-yl)amine]iron(ii) tris(dicyanomethylidene)methanediide |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462281/ https://www.ncbi.nlm.nih.gov/pubmed/36338914 http://dx.doi.org/10.1107/S241431462001278X |
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