Cargando…

Bis[tris­(pyridin-2-yl)amine]­iron(II) tris­(di­cyano­methyl­idene)methane­diide

In the title compound, [Fe{(C(5)H(4)N)(3)N}(2)][C{C(CN)(2)}(3)], both ions lie across centres of inversion, with the anion being statistically disordered over two sets of atomic sites having equal occupancy. The cation and anion have approximate [Image: see text] and 32 symmetry, respectively, and t...

Descripción completa

Detalles Bibliográficos
Autores principales: Setifi, Zouaoui, Setifi, Fatima, Dege, Necmi, Al-Douh, Mohammed Hadi, Glidewell, Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462281/
https://www.ncbi.nlm.nih.gov/pubmed/36338914
http://dx.doi.org/10.1107/S241431462001278X
_version_ 1784787149919354880
author Setifi, Zouaoui
Setifi, Fatima
Dege, Necmi
Al-Douh, Mohammed Hadi
Glidewell, Christopher
author_facet Setifi, Zouaoui
Setifi, Fatima
Dege, Necmi
Al-Douh, Mohammed Hadi
Glidewell, Christopher
author_sort Setifi, Zouaoui
collection PubMed
description In the title compound, [Fe{(C(5)H(4)N)(3)N}(2)][C{C(CN)(2)}(3)], both ions lie across centres of inversion, with the anion being statistically disordered over two sets of atomic sites having equal occupancy. The cation and anion have approximate [Image: see text] and 32 symmetry, respectively, and the Fe—N bond lengths indicate low-spin Fe(II). A combination of two-centre C—H⋯N and three-centre C—H⋯(N)(2) hydrogen bonds link the ions into complex sheets. Several low-occupancy water mol­ecules are present, whose H atoms could not be located: accordingly, the reflection data were subjected to the SQUEEZE procedure [Spek (2015 ▸). Acta Cryst. C71, 9–18]. [Image: see text]
format Online
Article
Text
id pubmed-9462281
institution National Center for Biotechnology Information
language English
publishDate 2020
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-94622812022-11-04 Bis[tris­(pyridin-2-yl)amine]­iron(II) tris­(di­cyano­methyl­idene)methane­diide Setifi, Zouaoui Setifi, Fatima Dege, Necmi Al-Douh, Mohammed Hadi Glidewell, Christopher IUCrdata Data Reports In the title compound, [Fe{(C(5)H(4)N)(3)N}(2)][C{C(CN)(2)}(3)], both ions lie across centres of inversion, with the anion being statistically disordered over two sets of atomic sites having equal occupancy. The cation and anion have approximate [Image: see text] and 32 symmetry, respectively, and the Fe—N bond lengths indicate low-spin Fe(II). A combination of two-centre C—H⋯N and three-centre C—H⋯(N)(2) hydrogen bonds link the ions into complex sheets. Several low-occupancy water mol­ecules are present, whose H atoms could not be located: accordingly, the reflection data were subjected to the SQUEEZE procedure [Spek (2015 ▸). Acta Cryst. C71, 9–18]. [Image: see text] International Union of Crystallography 2020-09-25 /pmc/articles/PMC9462281/ /pubmed/36338914 http://dx.doi.org/10.1107/S241431462001278X Text en © Setifi et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Setifi, Zouaoui
Setifi, Fatima
Dege, Necmi
Al-Douh, Mohammed Hadi
Glidewell, Christopher
Bis[tris­(pyridin-2-yl)amine]­iron(II) tris­(di­cyano­methyl­idene)methane­diide
title Bis[tris­(pyridin-2-yl)amine]­iron(II) tris­(di­cyano­methyl­idene)methane­diide
title_full Bis[tris­(pyridin-2-yl)amine]­iron(II) tris­(di­cyano­methyl­idene)methane­diide
title_fullStr Bis[tris­(pyridin-2-yl)amine]­iron(II) tris­(di­cyano­methyl­idene)methane­diide
title_full_unstemmed Bis[tris­(pyridin-2-yl)amine]­iron(II) tris­(di­cyano­methyl­idene)methane­diide
title_short Bis[tris­(pyridin-2-yl)amine]­iron(II) tris­(di­cyano­methyl­idene)methane­diide
title_sort bis[tris­(pyridin-2-yl)amine]­iron(ii) tris­(di­cyano­methyl­idene)methane­diide
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462281/
https://www.ncbi.nlm.nih.gov/pubmed/36338914
http://dx.doi.org/10.1107/S241431462001278X
work_keys_str_mv AT setifizouaoui bistrispyridin2ylamineironiitrisdicyanomethylidenemethanediide
AT setififatima bistrispyridin2ylamineironiitrisdicyanomethylidenemethanediide
AT degenecmi bistrispyridin2ylamineironiitrisdicyanomethylidenemethanediide
AT aldouhmohammedhadi bistrispyridin2ylamineironiitrisdicyanomethylidenemethanediide
AT glidewellchristopher bistrispyridin2ylamineironiitrisdicyanomethylidenemethanediide