Tetra­kis(di­cyclo­hexyl­amido)­zirconium(IV)

The reaction of ZrCl(4) with three equivalents of LiNCy(2) (Cy is cyclo­hex­yl) resulted in the formation of tris­(di­cyclo­hexyl­amido)­zirconium chloride and the title compound, [Zr(C(12)H(22)N)(4)]. The latter is isotypic with its cerium(IV) analogue and crystallizes with three independent mol­ec...

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Detalles Bibliográficos
Autores principales: Frerichs, Nils, Schmidtmann, Marc, Beckhaus, Rüdiger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462282/
https://www.ncbi.nlm.nih.gov/pubmed/36338916
http://dx.doi.org/10.1107/S2414314620011451
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author Frerichs, Nils
Schmidtmann, Marc
Beckhaus, Rüdiger
author_facet Frerichs, Nils
Schmidtmann, Marc
Beckhaus, Rüdiger
author_sort Frerichs, Nils
collection PubMed
description The reaction of ZrCl(4) with three equivalents of LiNCy(2) (Cy is cyclo­hex­yl) resulted in the formation of tris­(di­cyclo­hexyl­amido)­zirconium chloride and the title compound, [Zr(C(12)H(22)N)(4)]. The latter is isotypic with its cerium(IV) analogue and crystallizes with three independent mol­ecules in the asymmetric unit. One mol­ecule is located about a twofold rotation axis, and the other two on fourfold inversion axes. In each mol­ecule, the Zr(IV) atom has a distorted tetra­hedral coordination environment. The crystal under investigation was twinned by inversion in a 1:1 ratio. [Image: see text]
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spelling pubmed-94622822022-11-04 Tetra­kis(di­cyclo­hexyl­amido)­zirconium(IV) Frerichs, Nils Schmidtmann, Marc Beckhaus, Rüdiger IUCrdata Data Reports The reaction of ZrCl(4) with three equivalents of LiNCy(2) (Cy is cyclo­hex­yl) resulted in the formation of tris­(di­cyclo­hexyl­amido)­zirconium chloride and the title compound, [Zr(C(12)H(22)N)(4)]. The latter is isotypic with its cerium(IV) analogue and crystallizes with three independent mol­ecules in the asymmetric unit. One mol­ecule is located about a twofold rotation axis, and the other two on fourfold inversion axes. In each mol­ecule, the Zr(IV) atom has a distorted tetra­hedral coordination environment. The crystal under investigation was twinned by inversion in a 1:1 ratio. [Image: see text] International Union of Crystallography 2020-09-04 /pmc/articles/PMC9462282/ /pubmed/36338916 http://dx.doi.org/10.1107/S2414314620011451 Text en © Frerichs et al. 2020 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Frerichs, Nils
Schmidtmann, Marc
Beckhaus, Rüdiger
Tetra­kis(di­cyclo­hexyl­amido)­zirconium(IV)
title Tetra­kis(di­cyclo­hexyl­amido)­zirconium(IV)
title_full Tetra­kis(di­cyclo­hexyl­amido)­zirconium(IV)
title_fullStr Tetra­kis(di­cyclo­hexyl­amido)­zirconium(IV)
title_full_unstemmed Tetra­kis(di­cyclo­hexyl­amido)­zirconium(IV)
title_short Tetra­kis(di­cyclo­hexyl­amido)­zirconium(IV)
title_sort tetra­kis(di­cyclo­hexyl­amido)­zirconium(iv)
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462282/
https://www.ncbi.nlm.nih.gov/pubmed/36338916
http://dx.doi.org/10.1107/S2414314620011451
work_keys_str_mv AT frerichsnils tetrakisdicyclohexylamidozirconiumiv
AT schmidtmannmarc tetrakisdicyclohexylamidozirconiumiv
AT beckhausrudiger tetrakisdicyclohexylamidozirconiumiv

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