Bis(μ(4)-adamantane-1,3-di­carboxyl­ato-1κO (1):2κO (1′):3κO (3):4κO (3′))octa­carbonyl-1κ(2) C,2κ(2) C,3κ(2) C,4κ(2) C-tetra­kis­[tris­(4-methyl­phen­yl)phosphane]-1κP,2κP,3κP,4κP-tetra­osmium(I)(2 Os–Os)

The title complex, [{Os(2)(CO)(4)(C(21)H(21)P)(2)}(2)(C(12)H(14)O(4))(2)], is a centrosymmetric mol­ecular loop consisting of two Os—Os sawhorse units linked by two adamantane di­carboxyl­ato bridges. It was synthesized by the microwave-mediated reaction between Os(3)(CO)(12) and adamantane-1,3-di­c...

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Detalles Bibliográficos
Autores principales: Zometa Paniagua, Diego F., Powell, Gregory L., Powell, Cynthia B., Reinheimer, Eric W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462288/
https://www.ncbi.nlm.nih.gov/pubmed/36338913
http://dx.doi.org/10.1107/S2414314620012043

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462288/
https://www.ncbi.nlm.nih.gov/pubmed/36338913
http://dx.doi.org/10.1107/S2414314620012043

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