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Bis(μ(4)-adamantane-1,3-dicarboxylato-1κO (1):2κO (1′):3κO (3):4κO (3′))octacarbonyl-1κ(2) C,2κ(2) C,3κ(2) C,4κ(2) C-tetrakis[tris(4-methylphenyl)phosphane]-1κP,2κP,3κP,4κP-tetraosmium(I)(2 Os–Os)
The title complex, [{Os(2)(CO)(4)(C(21)H(21)P)(2)}(2)(C(12)H(14)O(4))(2)], is a centrosymmetric molecular loop consisting of two Os—Os sawhorse units linked by two adamantane dicarboxylato bridges. It was synthesized by the microwave-mediated reaction between Os(3)(CO)(12) and adamantane-1,3-dic...
Autores principales: | Zometa Paniagua, Diego F., Powell, Gregory L., Powell, Cynthia B., Reinheimer, Eric W. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462288/ https://www.ncbi.nlm.nih.gov/pubmed/36338913 http://dx.doi.org/10.1107/S2414314620012043 |
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