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[1,2-Bis(di­phenyl­phosphan­yl)ethane-κ(2) P,P]chlorido­(isonicotinamide-κN)palladium(II) nitrate aceto­nitrile monosolvate

The Pd(II) central atom in the title complex, [PdCl(C(26)H(24)P(2))(C(6)H(6)N(2)O)]NO(3)·CH(3)CN or [PdCl(dppe)(INAM)]NO(3)·CH(3)CN, where dppe is 1,2-bis­(di­phenyl­phosphan­yl)ethane and INAM is isonicotinamide, exists in a slightly distorted square-planar environment defined by the two P atoms of...

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Autores principales: Adrian, Rafael A., Lagemann, Bradley J., Arman, Hadi D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462291/
https://www.ncbi.nlm.nih.gov/pubmed/36337465
http://dx.doi.org/10.1107/S2414314621011718
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author Adrian, Rafael A.
Lagemann, Bradley J.
Arman, Hadi D.
author_facet Adrian, Rafael A.
Lagemann, Bradley J.
Arman, Hadi D.
author_sort Adrian, Rafael A.
collection PubMed
description The Pd(II) central atom in the title complex, [PdCl(C(26)H(24)P(2))(C(6)H(6)N(2)O)]NO(3)·CH(3)CN or [PdCl(dppe)(INAM)]NO(3)·CH(3)CN, where dppe is 1,2-bis­(di­phenyl­phosphan­yl)ethane and INAM is isonicotinamide, exists in a slightly distorted square-planar environment defined by the two P atoms of the dppe ligand, a chloride ligand and the N atom of the isonicotinamide pyridyl ring. The crystal packing in the structure is held together by hydrogen bonds between the amide of the INAM ligand and the nitrate ions that complete the outer coordination sphere. A mol­ecule of aceto­nitrile is also found in the asymmetric unit of the title complex. [Image: see text]
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spelling pubmed-94622912022-11-04 [1,2-Bis(di­phenyl­phosphan­yl)ethane-κ(2) P,P]chlorido­(isonicotinamide-κN)palladium(II) nitrate aceto­nitrile monosolvate Adrian, Rafael A. Lagemann, Bradley J. Arman, Hadi D. IUCrdata Data Reports The Pd(II) central atom in the title complex, [PdCl(C(26)H(24)P(2))(C(6)H(6)N(2)O)]NO(3)·CH(3)CN or [PdCl(dppe)(INAM)]NO(3)·CH(3)CN, where dppe is 1,2-bis­(di­phenyl­phosphan­yl)ethane and INAM is isonicotinamide, exists in a slightly distorted square-planar environment defined by the two P atoms of the dppe ligand, a chloride ligand and the N atom of the isonicotinamide pyridyl ring. The crystal packing in the structure is held together by hydrogen bonds between the amide of the INAM ligand and the nitrate ions that complete the outer coordination sphere. A mol­ecule of aceto­nitrile is also found in the asymmetric unit of the title complex. [Image: see text] International Union of Crystallography 2021-11-19 /pmc/articles/PMC9462291/ /pubmed/36337465 http://dx.doi.org/10.1107/S2414314621011718 Text en © Adrian et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Adrian, Rafael A.
Lagemann, Bradley J.
Arman, Hadi D.
[1,2-Bis(di­phenyl­phosphan­yl)ethane-κ(2) P,P]chlorido­(isonicotinamide-κN)palladium(II) nitrate aceto­nitrile monosolvate
title [1,2-Bis(di­phenyl­phosphan­yl)ethane-κ(2) P,P]chlorido­(isonicotinamide-κN)palladium(II) nitrate aceto­nitrile monosolvate
title_full [1,2-Bis(di­phenyl­phosphan­yl)ethane-κ(2) P,P]chlorido­(isonicotinamide-κN)palladium(II) nitrate aceto­nitrile monosolvate
title_fullStr [1,2-Bis(di­phenyl­phosphan­yl)ethane-κ(2) P,P]chlorido­(isonicotinamide-κN)palladium(II) nitrate aceto­nitrile monosolvate
title_full_unstemmed [1,2-Bis(di­phenyl­phosphan­yl)ethane-κ(2) P,P]chlorido­(isonicotinamide-κN)palladium(II) nitrate aceto­nitrile monosolvate
title_short [1,2-Bis(di­phenyl­phosphan­yl)ethane-κ(2) P,P]chlorido­(isonicotinamide-κN)palladium(II) nitrate aceto­nitrile monosolvate
title_sort [1,2-bis(di­phenyl­phosphan­yl)ethane-κ(2) p,p]chlorido­(isonicotinamide-κn)palladium(ii) nitrate aceto­nitrile monosolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462291/
https://www.ncbi.nlm.nih.gov/pubmed/36337465
http://dx.doi.org/10.1107/S2414314621011718
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