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[1,2-Bis(diphenylphosphanyl)ethane-κ(2) P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate
The Pd(II) central atom in the title complex, [PdCl(C(26)H(24)P(2))(C(6)H(6)N(2)O)]NO(3)·CH(3)CN or [PdCl(dppe)(INAM)]NO(3)·CH(3)CN, where dppe is 1,2-bis(diphenylphosphanyl)ethane and INAM is isonicotinamide, exists in a slightly distorted square-planar environment defined by the two P atoms of...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462291/ https://www.ncbi.nlm.nih.gov/pubmed/36337465 http://dx.doi.org/10.1107/S2414314621011718 |
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author | Adrian, Rafael A. Lagemann, Bradley J. Arman, Hadi D. |
author_facet | Adrian, Rafael A. Lagemann, Bradley J. Arman, Hadi D. |
author_sort | Adrian, Rafael A. |
collection | PubMed |
description | The Pd(II) central atom in the title complex, [PdCl(C(26)H(24)P(2))(C(6)H(6)N(2)O)]NO(3)·CH(3)CN or [PdCl(dppe)(INAM)]NO(3)·CH(3)CN, where dppe is 1,2-bis(diphenylphosphanyl)ethane and INAM is isonicotinamide, exists in a slightly distorted square-planar environment defined by the two P atoms of the dppe ligand, a chloride ligand and the N atom of the isonicotinamide pyridyl ring. The crystal packing in the structure is held together by hydrogen bonds between the amide of the INAM ligand and the nitrate ions that complete the outer coordination sphere. A molecule of acetonitrile is also found in the asymmetric unit of the title complex. [Image: see text] |
format | Online Article Text |
id | pubmed-9462291 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-94622912022-11-04 [1,2-Bis(diphenylphosphanyl)ethane-κ(2) P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate Adrian, Rafael A. Lagemann, Bradley J. Arman, Hadi D. IUCrdata Data Reports The Pd(II) central atom in the title complex, [PdCl(C(26)H(24)P(2))(C(6)H(6)N(2)O)]NO(3)·CH(3)CN or [PdCl(dppe)(INAM)]NO(3)·CH(3)CN, where dppe is 1,2-bis(diphenylphosphanyl)ethane and INAM is isonicotinamide, exists in a slightly distorted square-planar environment defined by the two P atoms of the dppe ligand, a chloride ligand and the N atom of the isonicotinamide pyridyl ring. The crystal packing in the structure is held together by hydrogen bonds between the amide of the INAM ligand and the nitrate ions that complete the outer coordination sphere. A molecule of acetonitrile is also found in the asymmetric unit of the title complex. [Image: see text] International Union of Crystallography 2021-11-19 /pmc/articles/PMC9462291/ /pubmed/36337465 http://dx.doi.org/10.1107/S2414314621011718 Text en © Adrian et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Data Reports Adrian, Rafael A. Lagemann, Bradley J. Arman, Hadi D. [1,2-Bis(diphenylphosphanyl)ethane-κ(2) P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate |
title | [1,2-Bis(diphenylphosphanyl)ethane-κ(2)
P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate |
title_full | [1,2-Bis(diphenylphosphanyl)ethane-κ(2)
P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate |
title_fullStr | [1,2-Bis(diphenylphosphanyl)ethane-κ(2)
P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate |
title_full_unstemmed | [1,2-Bis(diphenylphosphanyl)ethane-κ(2)
P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate |
title_short | [1,2-Bis(diphenylphosphanyl)ethane-κ(2)
P,P]chlorido(isonicotinamide-κN)palladium(II) nitrate acetonitrile monosolvate |
title_sort | [1,2-bis(diphenylphosphanyl)ethane-κ(2)
p,p]chlorido(isonicotinamide-κn)palladium(ii) nitrate acetonitrile monosolvate |
topic | Data Reports |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462291/ https://www.ncbi.nlm.nih.gov/pubmed/36337465 http://dx.doi.org/10.1107/S2414314621011718 |
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