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Bis(μ-cobaltoceniumselenolate-1:2κ(2) Se:Se)bis[bis(cobaltoceniumselenolate-κSe)mercury(II)] tetrakis(hexafluoridophosphate) acetonitrile disolvate
The title compound, [Co(6)Hg(2)(C(5)H(5))(6)(C(5)H(4)Se)(6)](PF(6))(4)·2CH(3)CN or [Hg(2)(CcSe)(6)][PF(6)](4)·2CH(3)CN (Cc = C(10)H(9)Co), was obtained as bright-orange needle-shaped crystals. It is a salt containing a tetracationic dimercury species with six cobaltoceniumselenolate ligands, four...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462298/ https://www.ncbi.nlm.nih.gov/pubmed/36340989 http://dx.doi.org/10.1107/S241431462101083X |
Sumario: | The title compound, [Co(6)Hg(2)(C(5)H(5))(6)(C(5)H(4)Se)(6)](PF(6))(4)·2CH(3)CN or [Hg(2)(CcSe)(6)][PF(6)](4)·2CH(3)CN (Cc = C(10)H(9)Co), was obtained as bright-orange needle-shaped crystals. It is a salt containing a tetracationic dimercury species with six cobaltoceniumselenolate ligands, four hexafluoridophosphate counter-ions and two acetonitrile solvent molecules. The cation (point group [Image: see text] ) has a bitetrahedral {Hg(2)Se(6)} core with two bridging Se atoms and four terminal Se atoms. [Image: see text] |
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