Bis(μ-cobaltoceniumseleno­late-1:2κ(2) Se:Se)bis[bis­(cobaltoceniumseleno­late-κSe)mercury(II)] tetra­kis­(hexa­fluorido­phosphate) aceto­nitrile disolvate

The title compound, [Co(6)Hg(2)(C(5)H(5))(6)(C(5)H(4)Se)(6)](PF(6))(4)·2CH(3)CN or [Hg(2)(CcSe)(6)][PF(6)](4)·2CH(3)CN (Cc = C(10)H(9)Co), was obtained as bright-orange needle-shaped crystals. It is a salt containing a tetra­cationic dimercury species with six cobaltoceniumseleno­late ligands, four...

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Detalles Bibliográficos
Autores principales: Menia, Daniel, Wurst, Klaus, Bildstein, Benno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2021
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462298/
https://www.ncbi.nlm.nih.gov/pubmed/36340989
http://dx.doi.org/10.1107/S241431462101083X
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author Menia, Daniel
Wurst, Klaus
Bildstein, Benno
author_facet Menia, Daniel
Wurst, Klaus
Bildstein, Benno
author_sort Menia, Daniel
collection PubMed
description The title compound, [Co(6)Hg(2)(C(5)H(5))(6)(C(5)H(4)Se)(6)](PF(6))(4)·2CH(3)CN or [Hg(2)(CcSe)(6)][PF(6)](4)·2CH(3)CN (Cc = C(10)H(9)Co), was obtained as bright-orange needle-shaped crystals. It is a salt containing a tetra­cationic dimercury species with six cobaltoceniumseleno­late ligands, four hexa­fluorido­phosphate counter-ions and two aceto­nitrile solvent mol­ecules. The cation (point group [Image: see text] ) has a bi­tetra­hedral {Hg(2)Se(6)} core with two bridging Se atoms and four terminal Se atoms. [Image: see text]
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spelling pubmed-94622982022-11-04 Bis(μ-cobaltoceniumseleno­late-1:2κ(2) Se:Se)bis[bis­(cobaltoceniumseleno­late-κSe)mercury(II)] tetra­kis­(hexa­fluorido­phosphate) aceto­nitrile disolvate Menia, Daniel Wurst, Klaus Bildstein, Benno IUCrdata Data Reports The title compound, [Co(6)Hg(2)(C(5)H(5))(6)(C(5)H(4)Se)(6)](PF(6))(4)·2CH(3)CN or [Hg(2)(CcSe)(6)][PF(6)](4)·2CH(3)CN (Cc = C(10)H(9)Co), was obtained as bright-orange needle-shaped crystals. It is a salt containing a tetra­cationic dimercury species with six cobaltoceniumseleno­late ligands, four hexa­fluorido­phosphate counter-ions and two aceto­nitrile solvent mol­ecules. The cation (point group [Image: see text] ) has a bi­tetra­hedral {Hg(2)Se(6)} core with two bridging Se atoms and four terminal Se atoms. [Image: see text] International Union of Crystallography 2021-10-21 /pmc/articles/PMC9462298/ /pubmed/36340989 http://dx.doi.org/10.1107/S241431462101083X Text en © Menia et al. 2021 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Menia, Daniel
Wurst, Klaus
Bildstein, Benno
Bis(μ-cobaltoceniumseleno­late-1:2κ(2) Se:Se)bis[bis­(cobaltoceniumseleno­late-κSe)mercury(II)] tetra­kis­(hexa­fluorido­phosphate) aceto­nitrile disolvate
title Bis(μ-cobaltoceniumseleno­late-1:2κ(2) Se:Se)bis[bis­(cobaltoceniumseleno­late-κSe)mercury(II)] tetra­kis­(hexa­fluorido­phosphate) aceto­nitrile disolvate
title_full Bis(μ-cobaltoceniumseleno­late-1:2κ(2) Se:Se)bis[bis­(cobaltoceniumseleno­late-κSe)mercury(II)] tetra­kis­(hexa­fluorido­phosphate) aceto­nitrile disolvate
title_fullStr Bis(μ-cobaltoceniumseleno­late-1:2κ(2) Se:Se)bis[bis­(cobaltoceniumseleno­late-κSe)mercury(II)] tetra­kis­(hexa­fluorido­phosphate) aceto­nitrile disolvate
title_full_unstemmed Bis(μ-cobaltoceniumseleno­late-1:2κ(2) Se:Se)bis[bis­(cobaltoceniumseleno­late-κSe)mercury(II)] tetra­kis­(hexa­fluorido­phosphate) aceto­nitrile disolvate
title_short Bis(μ-cobaltoceniumseleno­late-1:2κ(2) Se:Se)bis[bis­(cobaltoceniumseleno­late-κSe)mercury(II)] tetra­kis­(hexa­fluorido­phosphate) aceto­nitrile disolvate
title_sort bis(μ-cobaltoceniumseleno­late-1:2κ(2) se:se)bis[bis­(cobaltoceniumseleno­late-κse)mercury(ii)] tetra­kis­(hexa­fluorido­phosphate) aceto­nitrile disolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9462298/
https://www.ncbi.nlm.nih.gov/pubmed/36340989
http://dx.doi.org/10.1107/S241431462101083X
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AT wurstklaus bismcobaltoceniumselenolate12k2sesebisbiscobaltoceniumselenolateksemercuryiitetrakishexafluoridophosphateacetonitriledisolvate
AT bildsteinbenno bismcobaltoceniumselenolate12k2sesebisbiscobaltoceniumselenolateksemercuryiitetrakishexafluoridophosphateacetonitriledisolvate

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